Triangular Clusters of Molybdenum Coordinated with Diethylthiocarbamate: Synthesis, Structure and Solution Behavior

Pavel A. Petrov, Elena A. Golubitskaya, Marsel R. Gallyamov, Aleksandra Yu Andreeva, Taisiya S. Sukhikh, Maxim N. Sokolov

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

Two novel clusters [Mo3S4(dtc)3(μ-dtc)(L)] (where L = (CD3)2SO and tetrahydrothiophene, tht) were prepared and structurally characterized. The tht complex and its previously reported congener with L = py were studied by means of temperature-dependent 1H NMR spectroscopy, indicating order of lability tht ≫ py.

Original languageEnglish
Pages (from-to)451-457
Number of pages7
JournalJournal of Cluster Science
Volume29
Issue number3
DOIs
Publication statusPublished - 1 May 2018

Keywords

  • Clusters
  • Molybdenum
  • NMR
  • Sulphur
  • CUBANE-TYPE CLUSTERS
  • ALKYNOIC ACIDS
  • ENOL LACTONES
  • NITROARENES
  • CONDUCTORS
  • LIGANDS
  • MO3S7
  • SULFIDE CLUSTERS
  • PDMO3S4 CORE
  • CYCLIZATION

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