The synthesis of new functionalized 1,3,5-triazine-based stable bi- and trinitroxides of the 2,5-dihydroimidazole series

Elena V. Zaytseva, Yury V. Gatilov, Dmitrii G. Mazhukin

Research output: Contribution to journalArticlepeer-review

Abstract

New non-conjugated functionalized 2,5-dihydroimidazole-type bi- and trinitroxyl radicals are described. The synthesis of which was based on a nucleophilic substitution reaction between 2,4,6-trichloro-1,3,5-triazine or 2,4-dichloro-6-methoxy-1,3,5-triazine and spiro-fused 2,5-dihydroimidazole-type monoradicals bearing both a p-hydroxyaryl moiety at the C-4 atom of the heterocycle and a residue at the fourth position of the cyclohexane ring. The model tris-nitroxide with an unsubstituted cyclohexane unit was structurally characterized in the solid state.

Original languageEnglish
Pages (from-to)359-374
Number of pages16
JournalArkivoc
Volume2018
Issue number5
DOIs
Publication statusPublished - 4 Aug 2018

Keywords

  • 1,3,5-triazine-based nitroxides
  • 2,5-dihydroimidazoles
  • Biradicals
  • Organic free radicals
  • Triradicals
  • triradicals
  • 1,3,5-Triazine-based nitroxides
  • biradicals
  • SUBSTITUENT
  • PHASE
  • organic free radicals
  • LIQUID-CRYSTALS
  • RADICALS
  • DERIVATIVES
  • S-TRIAZINE

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