The liquid phase catalytic hydrogenation of furfural to furfuryl alcohol

Ksenia E. Salnikova, Valentina G. Matveeva, Yurii V. Larichev, Alexey V. Bykov, Galina N. Demidenko, Irina P. Shkileva, Mikhail G. Sulman

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

We report the hydrogenation of furfural (FF) to furfuryl alcohol (FA) with Pd-containing catalysts stabilized by hypercrosslinked polystyrene (HPS). FF is one of the major ingredients of biooil produced by biomass pyrolysis, while FA is a source of value-added chemicals, thus, creating an effective path from biomass to important compounds. Different palladium precursors (PdCl2(CH3CN)2, Pd(CH3COO)2) were used for the catalysts synthesis. The nature of the precursor influences the size of palladium nanoparticles. The TEM and SAXS data showed that when using PdCl2(CH3CN)2, a monomodal distribution of particles size with mean diameter 5.4 ± 1.2 nm was observed, whereas for Pd(CH3COO)2, multimodal particle size distribution with the mean particle sizes up to 13.8 ± 5.4 nm was observed. The comparison of the catalytic activities of Pd-containing catalysts indicated that the more disperse sample of palladium showed higher values of FF conversion and selectivity to FA because of small particles.

Original languageEnglish
Pages (from-to)142-148
Number of pages7
JournalCatalysis Today
Volume329
DOIs
Publication statusPublished - 1 Jun 2019

Keywords

  • Furfural
  • Furfuryl alcohol
  • Hydrogenation
  • Hypercrosslinked polystyrene
  • Palladium catalyst

Fingerprint Dive into the research topics of 'The liquid phase catalytic hydrogenation of furfural to furfuryl alcohol'. Together they form a unique fingerprint.

Cite this