The effect of microwave sintering on stability and oxygen mobility of praseodymium nickelates-cobaltites and their nanocomposites

V. A. Sadykov; N. F. Eremeev; V. A. Bolotov; Yu Yu Tanashev; Yu E. Fedorova; D. G. Amanbayeva; A. S. Bobin; E. M. Sadovskaya; V. S. Muzykantov; V. V. Pelipenko; A. I. Lukashevich; T. A. Krieger; A. V. Ishchenko; A. L. Smirnova

doi:10.1016/j.ssi.2016.02.003

The effect of microwave sintering on stability and oxygen mobility of praseodymium nickelates-cobaltites and their nanocomposites

V. A. Sadykov, N. F. Eremeev, V. A. Bolotov, Yu Yu Tanashev, Yu E. Fedorova, D. G. Amanbayeva, A. S. Bobin, E. M. Sadovskaya, V. S. Muzykantov, V. V. Pelipenko, A. I. Lukashevich, T. A. Krieger, A. V. Ishchenko, A. L. Smirnova

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Co-doped praseodymium nickelates PrNi₁ _- _xCo_xO₃ _- _δ and their composites with yttrium doped ceria Ce_0.9Y_0.1O₂ _- _δ are known to be promising materials for intermediate temperature solid oxide fuel cells and membranes for oxygen separation. Powdered samples were obtained via Pechini route and ultrasonic dispersion followed by mechanical activation. Pellets were sintered at 870-1100 °C by using microwave radiation. In comparison with conventionally sintered materials, the phase transition leading to Ruddlesden-Popper phase formation was shifted down for about 50 °C-100 °C. The effect of sintering by microwave radiation consisted of dramatically increased sample density, improved phase purity and enhanced oxygen mobility. When undesirable phase transitions at elevated sintering temperatures hinder gas-tight layers preparation, the microwave sintering technique can be used without any deterioration of transport properties of materials in comparison with conventional calcination.

Original language	English
Pages (from-to)	76-81
Number of pages	6
Journal	Solid State Ionics
Volume	288
DOIs	https://doi.org/10.1016/j.ssi.2016.02.003
Publication status	Published - May 2016

Keywords

Cathode nanocomposites
Isotope exchange
Microwave sintering
Oxygen mobility
Solid oxide fuel cells
Synthesis

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10.1016/j.ssi.2016.02.003

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Sadykov, V. A., Eremeev, N. F., Bolotov, V. A., Tanashev, Y. Y., Fedorova, Y. E., Amanbayeva, D. G., Bobin, A. S., Sadovskaya, E. M., Muzykantov, V. S., Pelipenko, V. V., Lukashevich, A. I., Krieger, T. A., Ishchenko, A. V., & Smirnova, A. L. (2016). The effect of microwave sintering on stability and oxygen mobility of praseodymium nickelates-cobaltites and their nanocomposites. Solid State Ionics, 288, 76-81. https://doi.org/10.1016/j.ssi.2016.02.003

Sadykov, V. A. ; Eremeev, N. F. ; Bolotov, V. A. ; Tanashev, Yu Yu ; Fedorova, Yu E. ; Amanbayeva, D. G. ; Bobin, A. S. ; Sadovskaya, E. M. ; Muzykantov, V. S. ; Pelipenko, V. V. ; Lukashevich, A. I. ; Krieger, T. A. ; Ishchenko, A. V. ; Smirnova, A. L. / The effect of microwave sintering on stability and oxygen mobility of praseodymium nickelates-cobaltites and their nanocomposites. In: Solid State Ionics. 2016 ; Vol. 288. pp. 76-81.

@article{0ac80861c6344e06b6d337bf7754f636,

title = "The effect of microwave sintering on stability and oxygen mobility of praseodymium nickelates-cobaltites and their nanocomposites",

abstract = "Co-doped praseodymium nickelates PrNi1 - xCoxO3 - δ and their composites with yttrium doped ceria Ce0.9Y0.1O2 - δ are known to be promising materials for intermediate temperature solid oxide fuel cells and membranes for oxygen separation. Powdered samples were obtained via Pechini route and ultrasonic dispersion followed by mechanical activation. Pellets were sintered at 870-1100 °C by using microwave radiation. In comparison with conventionally sintered materials, the phase transition leading to Ruddlesden-Popper phase formation was shifted down for about 50 °C-100 °C. The effect of sintering by microwave radiation consisted of dramatically increased sample density, improved phase purity and enhanced oxygen mobility. When undesirable phase transitions at elevated sintering temperatures hinder gas-tight layers preparation, the microwave sintering technique can be used without any deterioration of transport properties of materials in comparison with conventional calcination.",

keywords = "Cathode nanocomposites, Isotope exchange, Microwave sintering, Oxygen mobility, Solid oxide fuel cells, Synthesis",

author = "Sadykov, {V. A.} and Eremeev, {N. F.} and Bolotov, {V. A.} and Tanashev, {Yu Yu} and Fedorova, {Yu E.} and Amanbayeva, {D. G.} and Bobin, {A. S.} and Sadovskaya, {E. M.} and Muzykantov, {V. S.} and Pelipenko, {V. V.} and Lukashevich, {A. I.} and Krieger, {T. A.} and Ishchenko, {A. V.} and Smirnova, {A. L.}",

year = "2016",

month = may,

doi = "10.1016/j.ssi.2016.02.003",

language = "English",

volume = "288",

pages = "76--81",

journal = "Solid State Ionics",

issn = "0167-2738",

publisher = "Elsevier Science B.V.",

}

Sadykov, VA, Eremeev, NF, Bolotov, VA, Tanashev, YY, Fedorova, YE, Amanbayeva, DG, Bobin, AS, Sadovskaya, EM, Muzykantov, VS, Pelipenko, VV, Lukashevich, AI, Krieger, TA, Ishchenko, AV & Smirnova, AL 2016, 'The effect of microwave sintering on stability and oxygen mobility of praseodymium nickelates-cobaltites and their nanocomposites', Solid State Ionics, vol. 288, pp. 76-81. https://doi.org/10.1016/j.ssi.2016.02.003

The effect of microwave sintering on stability and oxygen mobility of praseodymium nickelates-cobaltites and their nanocomposites. / Sadykov, V. A.; Eremeev, N. F.; Bolotov, V. A.; Tanashev, Yu Yu; Fedorova, Yu E.; Amanbayeva, D. G.; Bobin, A. S.; Sadovskaya, E. M.; Muzykantov, V. S.; Pelipenko, V. V.; Lukashevich, A. I.; Krieger, T. A.; Ishchenko, A. V.; Smirnova, A. L.

In: Solid State Ionics, Vol. 288, 05.2016, p. 76-81.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - The effect of microwave sintering on stability and oxygen mobility of praseodymium nickelates-cobaltites and their nanocomposites

AU - Sadykov, V. A.

AU - Eremeev, N. F.

AU - Bolotov, V. A.

AU - Tanashev, Yu Yu

AU - Fedorova, Yu E.

AU - Amanbayeva, D. G.

AU - Bobin, A. S.

AU - Sadovskaya, E. M.

AU - Muzykantov, V. S.

AU - Pelipenko, V. V.

AU - Lukashevich, A. I.

AU - Krieger, T. A.

AU - Ishchenko, A. V.

AU - Smirnova, A. L.

PY - 2016/5

Y1 - 2016/5

N2 - Co-doped praseodymium nickelates PrNi1 - xCoxO3 - δ and their composites with yttrium doped ceria Ce0.9Y0.1O2 - δ are known to be promising materials for intermediate temperature solid oxide fuel cells and membranes for oxygen separation. Powdered samples were obtained via Pechini route and ultrasonic dispersion followed by mechanical activation. Pellets were sintered at 870-1100 °C by using microwave radiation. In comparison with conventionally sintered materials, the phase transition leading to Ruddlesden-Popper phase formation was shifted down for about 50 °C-100 °C. The effect of sintering by microwave radiation consisted of dramatically increased sample density, improved phase purity and enhanced oxygen mobility. When undesirable phase transitions at elevated sintering temperatures hinder gas-tight layers preparation, the microwave sintering technique can be used without any deterioration of transport properties of materials in comparison with conventional calcination.

AB - Co-doped praseodymium nickelates PrNi1 - xCoxO3 - δ and their composites with yttrium doped ceria Ce0.9Y0.1O2 - δ are known to be promising materials for intermediate temperature solid oxide fuel cells and membranes for oxygen separation. Powdered samples were obtained via Pechini route and ultrasonic dispersion followed by mechanical activation. Pellets were sintered at 870-1100 °C by using microwave radiation. In comparison with conventionally sintered materials, the phase transition leading to Ruddlesden-Popper phase formation was shifted down for about 50 °C-100 °C. The effect of sintering by microwave radiation consisted of dramatically increased sample density, improved phase purity and enhanced oxygen mobility. When undesirable phase transitions at elevated sintering temperatures hinder gas-tight layers preparation, the microwave sintering technique can be used without any deterioration of transport properties of materials in comparison with conventional calcination.

KW - Cathode nanocomposites

KW - Isotope exchange

KW - Microwave sintering

KW - Oxygen mobility

KW - Solid oxide fuel cells

KW - Synthesis

UR - http://www.scopus.com/inward/record.url?scp=84964940195&partnerID=8YFLogxK

U2 - 10.1016/j.ssi.2016.02.003

DO - 10.1016/j.ssi.2016.02.003

M3 - Article

AN - SCOPUS:84964940195

VL - 288

SP - 76

EP - 81

JO - Solid State Ionics

JF - Solid State Ionics

SN - 0167-2738

ER -

The effect of microwave sintering on stability and oxygen mobility of praseodymium nickelates-cobaltites and their nanocomposites

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