Complexes (HTMP)4[Bi4I16] · 2H2O · 2(CH3)2CO (I) and (HTMP)3[Bi5I18] · 5THF (II) have been synthesized by the reactions of BiI3 and 2,3,5,6-tetramethylpyrazine (TMP) in acetone and tetrahydrofuran (THF), respectively. The crystal structures of both compounds were determined by X-ray diffraction analysis (СIF files CCDC nos. 1817306 (I) and 1817307 (II)). In both cases, the complexes in the solid state feature supramolecular contacts between the π systems of the cations and iodide ligands of the anions.
|Number of pages||7|
|Journal||Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya|
|Publication status||Published - 1 Dec 2018|
- halide complexes
- supramolecular contacts
- X-ray diffraction analysis
- BISMUTH IODIDE