Tailoring Heterometallic Cluster Functional Building Blocks: Synthesis, Separation, Structural and DFT Studies of [Re6−xMoxSe8(CN)6]n−

Viktoria K. Muravieva; Yakov M. Gayfulin; Carmelo Prestipino; Pierric Lemoine; Maxim R. Ryzhikov; Vadim V. Yanshole; Stéphane Cordier; Nikolay G. Naumov

doi:10.1002/chem.201903321

Tailoring Heterometallic Cluster Functional Building Blocks: Synthesis, Separation, Structural and DFT Studies of [Re_6−xMo_xSe₈(CN)₆]ⁿ⁻

Viktoria K. Muravieva, Yakov M. Gayfulin, Carmelo Prestipino, Pierric Lemoine, Maxim R. Ryzhikov, Vadim V. Yanshole, Stéphane Cordier, Nikolay G. Naumov

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Influence of the metal core composition and geometry on the structure, spectroscopic properties and redox potentials was investigated for the first time for heterometallic (Re/Mo)₆ octahedral clusters. The discrete anionic clusters [Re_6-xMo_xSe₈(CN)₆]ⁿ⁻ (x=2, 3; n=4, 5) were obtained as individual salts. Their isomeric composition and bond-length distribution were inspected using a combination of single-crystal X-ray structure analysis, NMR, EXAFS, and DFT calculations.

Original language	English
Pages (from-to)	15040-15045
Number of pages	7
Journal	Chemistry - A European Journal
Volume	25
Issue number	66
Early online date	24 Oct 2019
DOIs	https://doi.org/10.1002/chem.201903321
Publication status	Published - 27 Nov 2019

Keywords

cluster compounds
electronic structure
EXAFS
heterometallic complexes
structure
MOLYBDENUM
OCTAHEDRAL CLUSTERS
X-RAY

Access to Document

10.1002/chem.201903321

Cite this

@article{d65e71d5e332484ea424ed919e030afd,

title = "Tailoring Heterometallic Cluster Functional Building Blocks: Synthesis, Separation, Structural and DFT Studies of [Re6−xMoxSe8(CN)6]n−",

abstract = "Influence of the metal core composition and geometry on the structure, spectroscopic properties and redox potentials was investigated for the first time for heterometallic (Re/Mo)6 octahedral clusters. The discrete anionic clusters [Re6-xMoxSe8(CN)6]n− (x=2, 3; n=4, 5) were obtained as individual salts. Their isomeric composition and bond-length distribution were inspected using a combination of single-crystal X-ray structure analysis, NMR, EXAFS, and DFT calculations.",

keywords = "cluster compounds, electronic structure, EXAFS, heterometallic complexes, structure, MOLYBDENUM, OCTAHEDRAL CLUSTERS, X-RAY",

author = "Muravieva, {Viktoria K.} and Gayfulin, {Yakov M.} and Carmelo Prestipino and Pierric Lemoine and Ryzhikov, {Maxim R.} and Yanshole, {Vadim V.} and St{\'e}phane Cordier and Naumov, {Nikolay G.}",

year = "2019",

month = nov,

day = "27",

doi = "10.1002/chem.201903321",

language = "English",

volume = "25",

pages = "15040--15045",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "Wiley-VCH Verlag",

number = "66",

}

TY - JOUR

T1 - Tailoring Heterometallic Cluster Functional Building Blocks

T2 - Synthesis, Separation, Structural and DFT Studies of [Re6−xMoxSe8(CN)6]n−

AU - Muravieva, Viktoria K.

AU - Gayfulin, Yakov M.

AU - Prestipino, Carmelo

AU - Lemoine, Pierric

AU - Ryzhikov, Maxim R.

AU - Yanshole, Vadim V.

AU - Cordier, Stéphane

AU - Naumov, Nikolay G.

PY - 2019/11/27

Y1 - 2019/11/27

N2 - Influence of the metal core composition and geometry on the structure, spectroscopic properties and redox potentials was investigated for the first time for heterometallic (Re/Mo)6 octahedral clusters. The discrete anionic clusters [Re6-xMoxSe8(CN)6]n− (x=2, 3; n=4, 5) were obtained as individual salts. Their isomeric composition and bond-length distribution were inspected using a combination of single-crystal X-ray structure analysis, NMR, EXAFS, and DFT calculations.

AB - Influence of the metal core composition and geometry on the structure, spectroscopic properties and redox potentials was investigated for the first time for heterometallic (Re/Mo)6 octahedral clusters. The discrete anionic clusters [Re6-xMoxSe8(CN)6]n− (x=2, 3; n=4, 5) were obtained as individual salts. Their isomeric composition and bond-length distribution were inspected using a combination of single-crystal X-ray structure analysis, NMR, EXAFS, and DFT calculations.

KW - cluster compounds

KW - electronic structure

KW - EXAFS

KW - heterometallic complexes

KW - structure

KW - MOLYBDENUM

KW - OCTAHEDRAL CLUSTERS

KW - X-RAY

UR - http://www.scopus.com/inward/record.url?scp=85074595795&partnerID=8YFLogxK

U2 - 10.1002/chem.201903321

DO - 10.1002/chem.201903321

M3 - Article

C2 - 31468567

AN - SCOPUS:85074595795

VL - 25

SP - 15040

EP - 15045

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 66

ER -

Tailoring Heterometallic Cluster Functional Building Blocks: Synthesis, Separation, Structural and DFT Studies of [Re_6−xMo_xSe₈(CN)₆]ⁿ⁻

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this