Synthesis, structure, and properties of compounds containing both octahedral rhenium cluster cations and anions

A. A. Ivanov; M. A. Shestopalov; K. A. Brylev; Yu A. Vorotnikov; P. E. Plyusnin; Yu V. Mironov

doi:10.1007/s11172-017-1750-7

Synthesis, structure, and properties of compounds containing both octahedral rhenium cluster cations and anions

A. A. Ivanov, M. A. Shestopalov, K. A. Brylev, Yu A. Vorotnikov, P. E. Plyusnin, Yu V. Mironov

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The compound [{Re₆S₈}(3,5-Me₂pzH)₆]₂[{Re₆S₈}Br₆]•9H₂O•4EtOH containing a cluster cation and a cluster anion in a 2: 1 ratio was synthesized by mixing an ethanol solution of the rhenium cluster complex [{Re₆S₈}(3,5-Me₂pzH)₆]Br₂•2(3,5-Me₂pzH) (pzH is pyrazole) with an aqueous solution of Cs₄[{Re₆S₈}Br₆]•2H₂O. The resulting compound was characterized by a combination of physicochemical methods. In particular, luminescence properties were studied and compared with those of the parent cluster complexes. A crystal suitable for single-crystal X-ray diffraction was obtained by layering these solutions. According to single-crystal X-ray diffraction analysis, this compound is composed of a cluster cation and a cluster anion (in a ratio of 1: 1) and also of Zundel cations (H₅O₂ ⁺) and solvate water molecules and is described by the formula (H₅O₂)₂[{Re₆S₈}(3,5-Me₂pzH)₆][{Re₆S₈}Br₆]•4H₂O.

Original language	English
Pages (from-to)	426-431
Number of pages	6
Journal	Russian Chemical Bulletin
Volume	66
Issue number	3
DOIs	https://doi.org/10.1007/s11172-017-1750-7
Publication status	Published - 1 Mar 2017

Keywords

3,5-dimethylpyrazole
crystal structure
luminescence
octahedral chalcogenide cluster complexes
rhenium
Zundel cation
Zundel catio
CRYSTAL-STRUCTURE
ORGANIC-LIGANDS
COMPLEXES
ENCAPSULATION
LUMINESCENCE PROPERTIES
FAMILY
CHALCOGENIDE CLUSTERS
SE
LIGANDS SYNTHESIS
X-RAY

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title = "Synthesis, structure, and properties of compounds containing both octahedral rhenium cluster cations and anions",

abstract = "The compound [{Re6S8}(3,5-Me2pzH)6]2[{Re6S8}Br6]•9H2O•4EtOH containing a cluster cation and a cluster anion in a 2: 1 ratio was synthesized by mixing an ethanol solution of the rhenium cluster complex [{Re6S8}(3,5-Me2pzH)6]Br2•2(3,5-Me2pzH) (pzH is pyrazole) with an aqueous solution of Cs4[{Re6S8}Br6]•2H2O. The resulting compound was characterized by a combination of physicochemical methods. In particular, luminescence properties were studied and compared with those of the parent cluster complexes. A crystal suitable for single-crystal X-ray diffraction was obtained by layering these solutions. According to single-crystal X-ray diffraction analysis, this compound is composed of a cluster cation and a cluster anion (in a ratio of 1: 1) and also of Zundel cations (H5O2 +) and solvate water molecules and is described by the formula (H5O2)2[{Re6S8}(3,5-Me2pzH)6][{Re6S8}Br6]•4H2O.",

keywords = "3,5-dimethylpyrazole, crystal structure, luminescence, octahedral chalcogenide cluster complexes, rhenium, Zundel cation, Zundel catio, CRYSTAL-STRUCTURE, ORGANIC-LIGANDS, COMPLEXES, ENCAPSULATION, LUMINESCENCE PROPERTIES, FAMILY, CHALCOGENIDE CLUSTERS, SE, LIGANDS SYNTHESIS, X-RAY",

author = "Ivanov, {A. A.} and Shestopalov, {M. A.} and Brylev, {K. A.} and Vorotnikov, {Yu A.} and Plyusnin, {P. E.} and Mironov, {Yu V.}",

year = "2017",

month = mar,

day = "1",

doi = "10.1007/s11172-017-1750-7",

language = "English",

volume = "66",

pages = "426--431",

journal = "Russian Chemical Bulletin",

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publisher = "Springer Nature",

number = "3",

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TY - JOUR

T1 - Synthesis, structure, and properties of compounds containing both octahedral rhenium cluster cations and anions

AU - Ivanov, A. A.

AU - Shestopalov, M. A.

AU - Brylev, K. A.

AU - Vorotnikov, Yu A.

AU - Plyusnin, P. E.

AU - Mironov, Yu V.

PY - 2017/3/1

Y1 - 2017/3/1

N2 - The compound [{Re6S8}(3,5-Me2pzH)6]2[{Re6S8}Br6]•9H2O•4EtOH containing a cluster cation and a cluster anion in a 2: 1 ratio was synthesized by mixing an ethanol solution of the rhenium cluster complex [{Re6S8}(3,5-Me2pzH)6]Br2•2(3,5-Me2pzH) (pzH is pyrazole) with an aqueous solution of Cs4[{Re6S8}Br6]•2H2O. The resulting compound was characterized by a combination of physicochemical methods. In particular, luminescence properties were studied and compared with those of the parent cluster complexes. A crystal suitable for single-crystal X-ray diffraction was obtained by layering these solutions. According to single-crystal X-ray diffraction analysis, this compound is composed of a cluster cation and a cluster anion (in a ratio of 1: 1) and also of Zundel cations (H5O2 +) and solvate water molecules and is described by the formula (H5O2)2[{Re6S8}(3,5-Me2pzH)6][{Re6S8}Br6]•4H2O.

AB - The compound [{Re6S8}(3,5-Me2pzH)6]2[{Re6S8}Br6]•9H2O•4EtOH containing a cluster cation and a cluster anion in a 2: 1 ratio was synthesized by mixing an ethanol solution of the rhenium cluster complex [{Re6S8}(3,5-Me2pzH)6]Br2•2(3,5-Me2pzH) (pzH is pyrazole) with an aqueous solution of Cs4[{Re6S8}Br6]•2H2O. The resulting compound was characterized by a combination of physicochemical methods. In particular, luminescence properties were studied and compared with those of the parent cluster complexes. A crystal suitable for single-crystal X-ray diffraction was obtained by layering these solutions. According to single-crystal X-ray diffraction analysis, this compound is composed of a cluster cation and a cluster anion (in a ratio of 1: 1) and also of Zundel cations (H5O2 +) and solvate water molecules and is described by the formula (H5O2)2[{Re6S8}(3,5-Me2pzH)6][{Re6S8}Br6]•4H2O.

KW - 3,5-dimethylpyrazole

KW - crystal structure

KW - luminescence

KW - octahedral chalcogenide cluster complexes

KW - rhenium

KW - Zundel cation

KW - Zundel catio

KW - CRYSTAL-STRUCTURE

KW - ORGANIC-LIGANDS

KW - COMPLEXES

KW - ENCAPSULATION

KW - LUMINESCENCE PROPERTIES

KW - FAMILY

KW - CHALCOGENIDE CLUSTERS

KW - SE

KW - LIGANDS SYNTHESIS

KW - X-RAY

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U2 - 10.1007/s11172-017-1750-7

DO - 10.1007/s11172-017-1750-7

M3 - Article

AN - SCOPUS:85029147749

VL - 66

SP - 426

EP - 431

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 3

ER -