Synthesis, Structure, and Luminescence Properties of a {Mo6I8} Complex with (C6F5)2PO2 Ligands

Alina D. Mironova, Maxim A. Mikhajlov, Taisiya S. Sukhikh, Konstantin A. Brylev, Artem L. Gushchin, Ilia V. Eltsov, Dmitri V. Stass, Evgeny I. Goryunov, Valery K. Brel, Maxim N. Sokolov

Research output: Contribution to journalArticlepeer-review

Abstract

Reaction of [Mo6I8(CH3COO)6]2– with bis(pentafluorophenyl)phosphinic acid HO(O)P(C6F5)2 yielded a new bright-red luminescent complex [{Mo6I8}(O2P(C6F5)2)6]2–, isolated as (Bu4N)(H5O2)[{Mo6I8}(O2P(C6F5)2)6]·3(Et2O)·1.5(acetone). It was characterized by X-ray analysis, CV, ESI-mass spectrometry, and NMR spectroscopy.

Original languageEnglish
Pages (from-to)1135-1140
Number of pages6
JournalZeitschrift fur Anorganische und Allgemeine Chemie
Volume645
Issue number18-19
DOIs
Publication statusPublished - 14 Oct 2019

Keywords

  • Electrochemistry
  • Luminescence
  • Molybdenum iodide cluster
  • Perfluorinated ligands
  • Phosphinic acids
  • BR
  • IODIDE CLUSTER
  • MOLYBDENUM CLUSTER COMPLEXES
  • SILICA NANOPARTICLES
  • REDOX
  • CL

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