Synthesis of Sulfones and Sulfoxides Based on (+)-usnic Acid

D. N. Sokolov, O. A. Luzina, N. F. Salakhutdinov

    Research output: Contribution to journalArticlepeer-review

    Abstract

    Sulfones were produced by meta-chloroperbenzoic-acid oxidation of the corresponding thioethers prepared from (+)-usnic acid. Reaction of the thioethers with H2O2 in the presence of VO(acac)2 formed a mixture of sulfoxide diastereomers. Possible chiral oxidation of the thioethers into sulfoxides was studied.

    Original languageEnglish
    Pages (from-to)46-49
    Number of pages4
    JournalChemistry of Natural Compounds
    Volume54
    Issue number1
    DOIs
    Publication statusPublished - 1 Jan 2018

    Keywords

    • (+)-usnic acid
    • chiral oxidation
    • sulfones
    • sulfoxidation
    • thioethers

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