Synthesis of Sulfones and Sulfoxides Based on (+)-usnic Acid

D. N. Sokolov; O. A. Luzina; N. F. Salakhutdinov

doi:10.1007/s10600-018-2256-8

Synthesis of Sulfones and Sulfoxides Based on (+)-usnic Acid

D. N. Sokolov, O. A. Luzina, N. F. Salakhutdinov

Research output: Contribution to journal › Article › peer-review

Abstract

Sulfones were produced by meta-chloroperbenzoic-acid oxidation of the corresponding thioethers prepared from (+)-usnic acid. Reaction of the thioethers with H₂O₂ in the presence of VO(acac)₂ formed a mixture of sulfoxide diastereomers. Possible chiral oxidation of the thioethers into sulfoxides was studied.

Original language	English
Pages (from-to)	46-49
Number of pages	4
Journal	Chemistry of Natural Compounds
Volume	54
Issue number	1
DOIs	https://doi.org/10.1007/s10600-018-2256-8
Publication status	Published - 1 Jan 2018

Keywords

(+)-usnic acid
chiral oxidation
sulfones
sulfoxidation
thioethers

Access to Document

10.1007/s10600-018-2256-8

Cite this

@article{e1765bd21e704907943b826b7dacc629,

title = "Synthesis of Sulfones and Sulfoxides Based on (+)-usnic Acid",

abstract = "Sulfones were produced by meta-chloroperbenzoic-acid oxidation of the corresponding thioethers prepared from (+)-usnic acid. Reaction of the thioethers with H2O2 in the presence of VO(acac)2 formed a mixture of sulfoxide diastereomers. Possible chiral oxidation of the thioethers into sulfoxides was studied.",

keywords = "(+)-usnic acid, chiral oxidation, sulfones, sulfoxidation, thioethers",

author = "Sokolov, {D. N.} and Luzina, {O. A.} and Salakhutdinov, {N. F.}",

year = "2018",

month = jan,

day = "1",

doi = "10.1007/s10600-018-2256-8",

language = "English",

volume = "54",

pages = "46--49",

journal = "Chemistry of Natural Compounds",

issn = "0009-3130",

publisher = "Springer New York",

number = "1",

}

TY - JOUR

T1 - Synthesis of Sulfones and Sulfoxides Based on (+)-usnic Acid

AU - Sokolov, D. N.

AU - Luzina, O. A.

AU - Salakhutdinov, N. F.

PY - 2018/1/1

Y1 - 2018/1/1

N2 - Sulfones were produced by meta-chloroperbenzoic-acid oxidation of the corresponding thioethers prepared from (+)-usnic acid. Reaction of the thioethers with H2O2 in the presence of VO(acac)2 formed a mixture of sulfoxide diastereomers. Possible chiral oxidation of the thioethers into sulfoxides was studied.

AB - Sulfones were produced by meta-chloroperbenzoic-acid oxidation of the corresponding thioethers prepared from (+)-usnic acid. Reaction of the thioethers with H2O2 in the presence of VO(acac)2 formed a mixture of sulfoxide diastereomers. Possible chiral oxidation of the thioethers into sulfoxides was studied.

KW - (+)-usnic acid

KW - chiral oxidation

KW - sulfones

KW - sulfoxidation

KW - thioethers

UR - http://www.scopus.com/inward/record.url?scp=85042067392&partnerID=8YFLogxK

U2 - 10.1007/s10600-018-2256-8

DO - 10.1007/s10600-018-2256-8

M3 - Article

AN - SCOPUS:85042067392

VL - 54

SP - 46

EP - 49

JO - Chemistry of Natural Compounds

JF - Chemistry of Natural Compounds

SN - 0009-3130

IS - 1

ER -

Synthesis of Sulfones and Sulfoxides Based on (+)-usnic Acid

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this