Synthesis of Polyfluorinated Tetraoxacalix[4]arenes by Reaction of Pentafluoronitrobenzene with Resorcinol, Orcinol, and Tetrafluororesorcinol

V. N. Kovtonyuk, H. Han, Yu V. Gatilov

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

Successive reactions of pentafluoronitrobenzene with resorcinol, orcinol, andtetrafluororesorcinol in acetonitrile in the presence of triethylamine affordedpolyfluorinated ABAB and ABAC tetraoxacalix[4]arenes. Analysis of the1H and 19F NMR spectraof the synthesized oxacalixarenes indicated high conformational mobility of theresorcinol and tetrafluororesorcinol fragments of their molecules due tointeraction with the solvent.

Original languageEnglish
Pages (from-to)1153-1159
Number of pages7
JournalRussian Journal of Organic Chemistry
Volume56
Issue number7
DOIs
Publication statusPublished - 1 Jul 2020

Keywords

  • conformational behavior
  • orcinol
  • pentafluoronitrobenzene
  • polyfluorinated tetraoxacalixarenes
  • resorcinol
  • tetrafluororesorcinol

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