Synthesis of novel labdanoid–Based macroheterocycles using click–Cycloaddition reaction protocol

Yurii V. Kharitonov, Makhmut M. Shakirov, Elvira E. Shults

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

A convenient synthetic method to diterpenoid dialkyne 18-propargyloxy-16-[(prop-2-yn-1-yloxi)methyl]labda-8(17),13,15-triene in the common yield of 34% from the natural plant diterpenoid lambertianic acid was developed. 1,2,3-Triazolyl containing macroheterocyclic compounds with an integrated diterpenoid fragment have been prepared by CuAAC reaction of the labdanoid dialkyne with organic diazides.

Original languageEnglish
Pages (from-to)117-122
Number of pages6
JournalMacroheterocycles
Volume10
Issue number1
DOIs
Publication statusPublished - 1 Jan 2017

Keywords

  • CuAAC-reaction
  • Dialkynes
  • Diazides
  • Diterpenoids
  • Lamberianic acid
  • Macrocycles

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