Synthesis of hydrocarbons by CO2 fluid conversion with hydrogen: Experimental modeling at 7.8 GPa and 1350°C

A. G. Sokol; A. A. Tomilenko; T. A. Bul’bak; N. V. Sobolev

doi:10.1134/S1028334X17120285

Synthesis of hydrocarbons by CO₂ fluid conversion with hydrogen: Experimental modeling at 7.8 GPa and 1350°C

A. G. Sokol, A. A. Tomilenko, T. A. Bul’bak, N. V. Sobolev

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Synthesis of hydrocarbons by the interaction of a CO₂ fluid with hydrogen mantle domains has been simulated in an experiment at 7.8 GPa and 1350°C. The synthesized fluid contains mainly aldehydes; lower amounts of ketones, alcohols, esters, and ethers; as well as noticeable amounts of isobutane and butane, alkenes, arenes, and polycyclic aromatic and heterocyclic hydrocarbons. The fluid is compositionally close to volatiles found in inclusions from mantle olivines and picroilmenites.

Original language	English
Pages (from-to)	1483-1487
Number of pages	5
Journal	Doklady Earth Sciences
Volume	477
Issue number	2
DOIs	https://doi.org/10.1134/S1028334X17120285
Publication status	Published - 1 Dec 2017

Keywords

CHROMATOGRAPHY-MASS SPECTROMETRY
YAKUTIAN KIMBERLITES
VOLATILE COMPONENTS
DIAMOND FORMATION
GAS
METHANATION
CONSTRAINTS
STABILITY
ORIGIN
AGES

Access to Document

10.1134/S1028334X17120285

Cite this

@article{383a72d8476f464099170a64e6231cf6,

title = "Synthesis of hydrocarbons by CO2 fluid conversion with hydrogen: Experimental modeling at 7.8 GPa and 1350°C",

abstract = "Synthesis of hydrocarbons by the interaction of a CO2 fluid with hydrogen mantle domains has been simulated in an experiment at 7.8 GPa and 1350°C. The synthesized fluid contains mainly aldehydes; lower amounts of ketones, alcohols, esters, and ethers; as well as noticeable amounts of isobutane and butane, alkenes, arenes, and polycyclic aromatic and heterocyclic hydrocarbons. The fluid is compositionally close to volatiles found in inclusions from mantle olivines and picroilmenites.",

keywords = "CHROMATOGRAPHY-MASS SPECTROMETRY, YAKUTIAN KIMBERLITES, VOLATILE COMPONENTS, DIAMOND FORMATION, GAS, METHANATION, CONSTRAINTS, STABILITY, ORIGIN, AGES",

author = "Sokol, {A. G.} and Tomilenko, {A. A.} and Bul{\textquoteright}bak, {T. A.} and Sobolev, {N. V.}",

year = "2017",

month = dec,

day = "1",

doi = "10.1134/S1028334X17120285",

language = "English",

volume = "477",

pages = "1483--1487",

journal = "Doklady Earth Sciences",

issn = "1028-334X",

publisher = "PLEIADES PUBLISHING INC",

number = "2",

}

TY - JOUR

T1 - Synthesis of hydrocarbons by CO2 fluid conversion with hydrogen

T2 - Experimental modeling at 7.8 GPa and 1350°C

AU - Sokol, A. G.

AU - Tomilenko, A. A.

AU - Bul’bak, T. A.

AU - Sobolev, N. V.

PY - 2017/12/1

Y1 - 2017/12/1

N2 - Synthesis of hydrocarbons by the interaction of a CO2 fluid with hydrogen mantle domains has been simulated in an experiment at 7.8 GPa and 1350°C. The synthesized fluid contains mainly aldehydes; lower amounts of ketones, alcohols, esters, and ethers; as well as noticeable amounts of isobutane and butane, alkenes, arenes, and polycyclic aromatic and heterocyclic hydrocarbons. The fluid is compositionally close to volatiles found in inclusions from mantle olivines and picroilmenites.

AB - Synthesis of hydrocarbons by the interaction of a CO2 fluid with hydrogen mantle domains has been simulated in an experiment at 7.8 GPa and 1350°C. The synthesized fluid contains mainly aldehydes; lower amounts of ketones, alcohols, esters, and ethers; as well as noticeable amounts of isobutane and butane, alkenes, arenes, and polycyclic aromatic and heterocyclic hydrocarbons. The fluid is compositionally close to volatiles found in inclusions from mantle olivines and picroilmenites.

KW - CHROMATOGRAPHY-MASS SPECTROMETRY

KW - YAKUTIAN KIMBERLITES

KW - VOLATILE COMPONENTS

KW - DIAMOND FORMATION

KW - GAS

KW - METHANATION

KW - CONSTRAINTS

KW - STABILITY

KW - ORIGIN

KW - AGES

UR - http://www.scopus.com/inward/record.url?scp=85039980537&partnerID=8YFLogxK

U2 - 10.1134/S1028334X17120285

DO - 10.1134/S1028334X17120285

M3 - Article

AN - SCOPUS:85039980537

VL - 477

SP - 1483

EP - 1487

JO - Doklady Earth Sciences

JF - Doklady Earth Sciences

SN - 1028-334X

IS - 2

ER -

Synthesis of hydrocarbons by CO₂ fluid conversion with hydrogen: Experimental modeling at 7.8 GPa and 1350°C

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this