Synthesis of azolyl-substituted derivatives of 1-adamantanecarboxylic acid

Andrei Potapov

Research output: Chapter in Book/Report/Conference proceedingConference contributionResearchpeer-review

Abstract

Ligands containing azole rings are interesting as ligands for coordination chemistry, especially as building blocks for metal-organic frameworks. Adamantane can serve as a rigid linker for the construction of multidentate ligands. In this work we describe the synthesis of 3-azolyl-1-adamantanecaroboxylic acid derivatives starting from 3-bromo-1-adamantanecaroboxylic acid and the corresponding azoles (pyrazole, imidazole, 1,2,4-triazole, benzimidazole, 1,2,3-benzotriazole). The structure of products was confirmed by NMR and mass-spectrometry.

Original languageEnglish
Title of host publication20TH INTERNATIONAL ELECTRONIC CONFERENCE ON SYNTHETIC ORGANIC CHEMISTRY (ECSOC)
EditorsJA Seijas, MPV Tato, SK Lin
PublisherMDPI AG
Number of pages9
DOIs
Publication statusPublished - 2016
Externally publishedYes
Event20th International Electronic Conference on Synthetic Organic Chemistry -
Duration: 1 Nov 201630 Nov 2016

Conference

Conference20th International Electronic Conference on Synthetic Organic Chemistry
Period01.11.201630.11.2016

Keywords

  • adamantane
  • carboxylic acid
  • pyrazole
  • imidazole
  • triazole
  • ANTIVIRAL ACTIVITY
  • ADAMANTANE
  • DIAMONDOIDS
  • COMPLEXES
  • SCAFFOLDS
  • TECTONS

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