Synthesis of azolyl-substituted adamantane derivatives and their coordination compounds

D. I. Pavlov, T. S. Sukhikh, A. S. Potapov

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

Reactions of adamantylazoles with nucleophiles (water, carbon monoxide, acetonitrile) in sulfuric acid were studied. New bifunctional adamantane derivatives containing one heterocyclic substituent and one hydroxyl or acetamide substituent were synthesized. The coordination compounds of copper(II) and zinc(II) with 1-adamantyl-1,2,4-triazole, 4-adamantylpyrazole, and 4-adamantyl-3,5-dimethylpyrazole were synthesized and structurally characterized. These complexes are first examples of coordination compounds of azolyladamantanes.

Original languageEnglish
Pages (from-to)1953-1964
Number of pages12
JournalRussian Chemical Bulletin
Volume69
Issue number10
DOIs
Publication statusPublished - 1 Oct 2020

Keywords

  • adamantane
  • coordination compounds
  • copper
  • pyrazole
  • triazole
  • X-ray diffraction
  • zinc

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