Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo3S4Ga cores

Pavel A. Petrov, Dmitry Yu Naumov, Taisiya S. Sukhikh, Sergey N. Konchenko, Carlos J. Gómez-García, Rosa Llusar

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

Electron precise [Mo33-S)(μ-S)3(diphos)3Br3]Br (diphos = dppe, dmpe) incomplete cuboidal clusters with six cluster skeletal electrons (CSE) were converted into paramagnetic cuboidal [Mo3(GaBr)(μ3-S)4(diphos)3Br3] clusters by treatment with elemental Ga. The new heterobimetallic complexes with nine CSE possess a doublet ground state with the unpaired electron density delocalized over the three molybdenum atoms.

Original languageEnglish
Pages (from-to)7849-7852
Number of pages4
JournalNew Journal of Chemistry
Volume41
Issue number16
DOIs
Publication statusPublished - 21 Aug 2017

Keywords

  • X-RAY-STRUCTURE
  • MIXED-METAL CLUSTER
  • SHARED DOUBLE CUBE
  • MOLYBDENUM
  • COMPLEXES
  • DERIVATIVES
  • REACTIVITY
  • SINGLE
  • MO

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