Synthesis, crystal structure, and luminescent properties of novel zinc metal-organic frameworks based on 1,3-Bis(1, 2, 4-triazol-1-yl)propane

Evgeny Yu Semitut, Taisiya S. Sukhikh, Evgeny Yu Filatov, Galina A. Anosova, Alexey A. Ryadun, Konstantin A. Kovalenko, Andrei S. Potapov

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

Three new zinc three-dimensional coordination polymers with flexible 1, 3-bis(1, 2, 4-triazol-1-yl)propane ligand were synthesized. The crystal structures of synthesized compounds were determined, and structural peculiarities are discussed. Coordination compounds with composition [Zn(btrp)(bdc)] DMF are interpenetrated frameworks, while metal-organic framework (MOF) [Zn3(btrp)(bdc)3] DMF is not. Thermal stability and luminescent properties of synthesized compounds have been investigated. The possibility of usage of such compounds as sensitive materials for some aromatic compounds are explored, and it was shown that luminescence of coordination polymers is completely quenched in the presence of nitrobenzene. Sorption properties of synthesized MOFs toward nitrogen, carbon dioxide, and hydrogen were evaluated.

Original languageEnglish
Pages (from-to)5559-5567
Number of pages9
JournalCrystal Growth and Design
Volume17
Issue number10
DOIs
Publication statusPublished - Oct 2017

Keywords

  • N-DONOR LIGANDS
  • COORDINATION POLYMERS
  • SEPARATION
  • COMPLEXES
  • TRANSFORMATIONS
  • ADSORPTION
  • FEATURES
  • DESIGN
  • SERIES
  • 2D

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