Synthesis and structure of new Er(III) complex with N,N′-1,3-BIS(2,6-diisopropylphenyl)triazenide

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Abstract

By the interaction of [Er(N(SiMe3)2)3] with HN3Dipp ((N3Dipp) = N,N′-1,3-bis(2,6-diisopropylphenyl) triazenide) [Er(N3Dipp)(N(SiMe3)2)2] (1) and [Er(N3Dipp)2(N(SiMe3)2)] (2) complexes are obtained. The reaction of 2 with thiophenol gives [Er(N3Dipp)2(SPh)(THF)] complex (3). The structures of the compounds is determined by single crystal Xray diffraction of the following solid phases: 1, 2·C6H6, and 3.

Original languageEnglish
Pages (from-to)277-284
Number of pages8
JournalJournal of Structural Chemistry
Volume62
Issue number2
DOIs
Publication statusPublished - Feb 2021

Keywords

  • coordination compounds
  • crystal structure
  • erbium
  • lanthanides
  • synthesis
  • triazenes

OECD FOS+WOS

  • 2.05 MATERIALS ENGINEERING
  • 1.04 CHEMICAL SCIENCES

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