Synthesis and Structure of [Fe3(μ3-Q)(μ3-AsN(i-Bu)2)(CO)9] (Q = Se, Te) Clusters and Products of Their Hydrolysis

D. A. Bashirov; T. S. Sukhikh; N. V. Kuratieva; S. N. Konchenko

doi:10.1134/S0022476620020134

Synthesis and Structure of [Fe₃(μ₃-Q)(μ₃-AsN(i-Bu)₂)(CO)₉] (Q = Se, Te) Clusters and Products of Their Hydrolysis

D. A. Bashirov, T. S. Sukhikh, N. V. Kuratieva, S. N. Konchenko

Research output: Contribution to journal › Article › peer-review

Abstract

New iron clusters [Fe₃(μ₃-Q)(μ₃-AsN(i-Bu)₂)(CO)₉] (Q = Se (1a) and Te (1b)) are synthesized. Hydrolysis reactions of these compounds that break the As-N bond are studied. The structures of clusters 1a,b and products of hydrolysis, namely [Fe6(μ₆,η²-AsOAs)(μ₃-Te)₂(CO)₁₈] (2), [NH₂(i-Bu)₂][Fe₃(μ₃-Se)×× (μ₃-AsO)(CO)₉] (3), and [{Fe₃(μ₃-Se)(μ₄-As)(CO)₉}₂{Fe₂(μ₂-Se)₂ (CO)₅}] (4) are determined by the single crystal X-ray diffraction analysis.

Original language	English
Pages (from-to)	283-292
Number of pages	10
Journal	Journal of Structural Chemistry
Volume	61
Issue number	2
DOIs	https://doi.org/10.1134/S0022476620020134
Publication status	Published - 1 Feb 2020

Keywords

arsenic
carbonyl cluster
chalcogen
crystal structure
iron
synthesis
ELECTROCHEMICAL PROPERTIES
MOLECULAR-STRUCTURE
COMPLEXES
(MU-H)(2)FE-3(MU(3)-SE)(CO)(9)
IRON
CRYSTAL
MODELS
PROTON REDUCTION
METAL SUBSTITUTION-REACTION
TELLURIDE

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@article{09b03b30777d4bed97a5f8fee3a8c48f,

title = "Synthesis and Structure of [Fe3(μ3-Q)(μ3-AsN(i-Bu)2)(CO)9] (Q = Se, Te) Clusters and Products of Their Hydrolysis",

abstract = "New iron clusters [Fe3(μ3-Q)(μ3-AsN(i-Bu)2)(CO)9] (Q = Se (1a) and Te (1b)) are synthesized. Hydrolysis reactions of these compounds that break the As-N bond are studied. The structures of clusters 1a,b and products of hydrolysis, namely [Fe6(μ6,η2-AsOAs)(μ3-Te)2(CO)18] (2), [NH2(i-Bu)2][Fe3(μ3-Se)×× (μ3-AsO)(CO)9] (3), and [{Fe3(μ3-Se)(μ4-As)(CO)9}2{Fe2(μ2-Se)2 (CO)5}] (4) are determined by the single crystal X-ray diffraction analysis.",

keywords = "arsenic, carbonyl cluster, chalcogen, crystal structure, iron, synthesis, ELECTROCHEMICAL PROPERTIES, MOLECULAR-STRUCTURE, COMPLEXES, (MU-H)(2)FE-3(MU(3)-SE)(CO)(9), IRON, CRYSTAL, MODELS, PROTON REDUCTION, METAL SUBSTITUTION-REACTION, TELLURIDE",

author = "Bashirov, {D. A.} and Sukhikh, {T. S.} and Kuratieva, {N. V.} and Konchenko, {S. N.}",

year = "2020",

month = feb,

day = "1",

doi = "10.1134/S0022476620020134",

language = "English",

volume = "61",

pages = "283--292",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "2",

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TY - JOUR

T1 - Synthesis and Structure of [Fe3(μ3-Q)(μ3-AsN(i-Bu)2)(CO)9] (Q = Se, Te) Clusters and Products of Their Hydrolysis

AU - Bashirov, D. A.

AU - Sukhikh, T. S.

AU - Kuratieva, N. V.

AU - Konchenko, S. N.

PY - 2020/2/1

Y1 - 2020/2/1

N2 - New iron clusters [Fe3(μ3-Q)(μ3-AsN(i-Bu)2)(CO)9] (Q = Se (1a) and Te (1b)) are synthesized. Hydrolysis reactions of these compounds that break the As-N bond are studied. The structures of clusters 1a,b and products of hydrolysis, namely [Fe6(μ6,η2-AsOAs)(μ3-Te)2(CO)18] (2), [NH2(i-Bu)2][Fe3(μ3-Se)×× (μ3-AsO)(CO)9] (3), and [{Fe3(μ3-Se)(μ4-As)(CO)9}2{Fe2(μ2-Se)2 (CO)5}] (4) are determined by the single crystal X-ray diffraction analysis.

AB - New iron clusters [Fe3(μ3-Q)(μ3-AsN(i-Bu)2)(CO)9] (Q = Se (1a) and Te (1b)) are synthesized. Hydrolysis reactions of these compounds that break the As-N bond are studied. The structures of clusters 1a,b and products of hydrolysis, namely [Fe6(μ6,η2-AsOAs)(μ3-Te)2(CO)18] (2), [NH2(i-Bu)2][Fe3(μ3-Se)×× (μ3-AsO)(CO)9] (3), and [{Fe3(μ3-Se)(μ4-As)(CO)9}2{Fe2(μ2-Se)2 (CO)5}] (4) are determined by the single crystal X-ray diffraction analysis.

KW - arsenic

KW - carbonyl cluster

KW - chalcogen

KW - crystal structure

KW - iron

KW - synthesis

KW - ELECTROCHEMICAL PROPERTIES

KW - MOLECULAR-STRUCTURE

KW - COMPLEXES

KW - (MU-H)(2)FE-3(MU(3)-SE)(CO)(9)

KW - IRON

KW - CRYSTAL

KW - MODELS

KW - PROTON REDUCTION

KW - METAL SUBSTITUTION-REACTION

KW - TELLURIDE

UR - http://www.scopus.com/inward/record.url?scp=85087946601&partnerID=8YFLogxK

U2 - 10.1134/S0022476620020134

DO - 10.1134/S0022476620020134

M3 - Article

AN - SCOPUS:85087946601

VL - 61

SP - 283

EP - 292

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 2

ER -