Synthesis and Electrochemical Properties of ((CH3)2NH2)7[P2W17NbO62]

A. A. Shmakova, A. L. Gushchin, P. A. Abramov, M. N. Sokolov

Research output: Contribution to journalArticlepeer-review

Abstract

The bis(oxalate) complex of niobium (NH4)[NbO(C2O4)2(H2O)2]·3H2O can be used as a source of niobium to incorporate the {NbO}3+ group into a cavity of the monolacunary Dawson-type [α2-P2W17O61]10− anion. The product is isolated from the reaction mixture as dimethylammonium salt (Me2NH2)72-P2W17NbO62]·3H2O (1) and characterized by single crystal XRD, IR and Raman spectroscopy, and elemental analysis. (NBu4)6(Me2NH2)[α2-P2W17NbO62] (2) is obtained by adding Bu4NBr to an aqueous solution of 1. The comparison of the electrochemical properties of complex 2 and (NBu4)6[P2W18O62] shows that the incorporation of niobium atom hinders the anion reduction.

Original languageEnglish
Pages (from-to)961-966
Number of pages6
JournalJournal of Structural Chemistry
Volume60
Issue number6
DOIs
Publication statusPublished - 1 Jun 2019

Keywords

  • cyclic voltammetric patterns
  • Dawson anion
  • niobium
  • NMR
  • POLYOXOMETALATE
  • CATALYST

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