Synthesis and crystal structure of the coordination polymer [{Li(H2O)3}2(C36H36N24O12)]Cl2•6H2O

E. A. Kovalenko, D. G. Samsonenko, V. P. Fedin

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

The coordination polymer of the composition [{Li(H2O)3}2(C36H36N24O12)]Cl2•6H2O (1) was synthesized by heating an aqueous solution of lithium chloride and cucurbit[6]uril (CB[6]). According to single-crystal X-ray diffraction data, solvated lithium cations in compound 1 form coordination bonds with oxygen atoms of CB[6] molecules. Compound 1 was characterized by X-ray diffraction, IR spectroscopy, thermogravimetric and elemental analysis. Luminescence spectra of the new compound were measured.

Original languageEnglish
Pages (from-to)127-130
Number of pages4
JournalRussian Chemical Bulletin
Volume67
Issue number1
DOIs
Publication statusPublished - 1 Jan 2018

Keywords

  • crystal structure
  • cucurbit[6]uril
  • lithium
  • supramolecular chemistry
  • X-ray diffraction
  • ION COMPLEXED CUCURBITURIL
  • CALIXARENES
  • FRAMEWORKS

Fingerprint

Dive into the research topics of 'Synthesis and crystal structure of the coordination polymer [{Li(H<sub>2</sub>O)<sub>3</sub>}<sub>2</sub>(C<sub>36</sub>H<sub>36</sub>N<sub>24</sub>O<sub>12</sub>)]Cl<sub>2</sub>•6H<sub>2</sub>O'. Together they form a unique fingerprint.

Cite this