Study of the Reactions of Fullerene С60 with the Palladium-Containing Clusters of Molybdenum {Mo3PdS4} by Spectroscopic and Calculation Methods

Yu A. Laricheva, N. Yu Shmelev, A. L. Gushchin, M. N. Sokolov

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

The fabrication of hybrid materials combining the physicochemical properties of various classes is a complicated but promising trend for the development of the modern science. The formation of new hybrid cluster cations [Mo3Pd(C60)S4Cl3(R2Bipy)3]+ and [{Mo3PdS4Cl3(R2Bipy)3}2(C60)]2+ (Bipy is 2,2-bipyridine) containing fullerene C60 coordinated to the palladium atom by the reaction of [Mo3S4Cl3(R2Bipy)3]PF6 with Pd2(Dba)3 (Dba is dibenzylideneacetone) and C60 is shown by a complex of physicochemical methods. The reaction products are studied by IR and NMR (1H, 31Р, and C–H correlations) spectroscopy and mass spectrometry. The quantum-chemical calculations are performed by the DFT method for the correct interpretation of the spectroscopic data and elucidation of the electronic structures of the fullerene-containing compounds.

Original languageEnglish
Pages (from-to)196-203
Number of pages8
JournalRussian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume47
Issue number3
DOIs
Publication statusPublished - Mar 2021

Keywords

  • cluster complexes
  • DFT calculations
  • fullerene
  • molybdenum
  • palladium

OECD FOS+WOS

  • 2.04 CHEMICAL ENGINEERING
  • 1.04 CHEMICAL SCIENCES
  • 1.04.EC CHEMISTRY, INORGANIC & NUCLEAR

Fingerprint

Dive into the research topics of 'Study of the Reactions of Fullerene С<sub>60</sub> with the Palladium-Containing Clusters of Molybdenum {Mo<sub>3</sub>PdS<sub>4</sub>} by Spectroscopic and Calculation Methods'. Together they form a unique fingerprint.

Cite this