Study of an SmBO3-ScBO3system and new SmSc(BO3)2orthoborate

Artem B. Kuznetsov, Konstantin A. Kokh, Nadezda G. Kononova, Vyacheslav S. Shevchenko, Ssergey V. Rashchenko, Ivan N. Lapin, Valery A. Svetlichnyi, Bolat Uralbekov, Asset Bolatov, Ekaterina A. Simonova, Alexander E. Kokh

Research output: Contribution to journalArticlepeer-review

Abstract

A new SmSc(BO3)2compound was discovered from the study of SmBO3-ScBO3by solid-state synthesis. The obtained compound was grown from a stoichiometric melt by a spontaneous crystallization method, and crystallizes in the space groupR3̄ with the cell parameters ofa= 4.8951(6) Å andc= 16.3012(2) Å. In addition, phase equilibria in this system in the 900-1300 °C temperature range were studied by X-ray diffraction and thermal analyses, as well as special diffusion experiments.

Original languageEnglish
Pages (from-to)1482-1488
Number of pages7
JournalCrystEngComm
Volume23
Issue number6
DOIs
Publication statusPublished - 14 Feb 2021

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