Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp2Mo2(CO)4(η2-P2)] Complex and Silver(I) Salts

Mehdi Elsayed Moussa; Martin Fleischmann; Eugenia V. Peresypkina; Luis Dütsch; Michael Seidl; Gabor Balázs; Manfred Scheer

doi:10.1002/ejic.201700646

Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp₂Mo₂(CO)₄(η²-P₂)] Complex and Silver(I) Salts

Mehdi Elsayed Moussa, Martin Fleischmann, Eugenia V. Peresypkina, Luis Dütsch, Michael Seidl, Gabor Balázs, Manfred Scheer

Laboratory for Research Methods in Composition and Structure of Functional Materials

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The reactions of the tetrahedral diphosphorus [Cp₂Mo₂(CO)₄(η²-P₂)] (1; Cp = C₅H₅) complex with Ag[Al{OC(CF₃)₃}₄] (AgTEF) (A) and Ag[FAl{OC(C₆F₅)(C₆F₁₀)}₃] (AgFAl) (B) were studied. The first reaction led to the formation of the [Ag₂(η²-1)₂(η¹:η¹-1)₂][TEF]₂ (2) dimer and the [Ag₂(η¹:η¹-1)₃]_n[TEF]_2n (3) coordination polymer, whereas the second reaction afforded the [Ag₂(η¹:η¹-1)₂(η¹-CH₂Cl₂)₂(η²-C₇H₈)₂][FAl]₂ (4) or the [Ag₂(η²-1)₂(η¹:η¹-1)₂][FAl]₂ (5) dimer and the [Ag₂(η¹:η¹-1)₄]_n[FAl]_2n (6) coordination polymer. In each case, the products obtained depended on the ratio of the reactants and/or the synthetic procedure.

Original language	English
Pages (from-to)	3222-3226
Number of pages	5
Journal	European Journal of Inorganic Chemistry
Volume	2017
Issue number	25
DOIs	https://doi.org/10.1002/ejic.201700646
Publication status	Published - 7 Jul 2017

Keywords

Coordinating anions
Coordination polymers
Phosphorus
Silver
Synthetic methods
MOLECULE
LIGAND COMPLEXES
NMR-SPECTROSCOPY
BUILDING-BLOCKS
BEHAVIOR
ORGANIC HYBRID MATERIALS
ONE-DIMENSIONAL POLYMERS
FRAMEWORKS
PENTAPHOSPHAFERROCENE
CHEMISTRY

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Elsayed Moussa, M., Fleischmann, M., Peresypkina, E. V., Dütsch, L., Seidl, M., Balázs, G., & Scheer, M. (2017). Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp₂Mo₂(CO)₄(η²-P₂)] Complex and Silver(I) Salts. European Journal of Inorganic Chemistry, 2017(25), 3222-3226. https://doi.org/10.1002/ejic.201700646

Elsayed Moussa, Mehdi ; Fleischmann, Martin ; Peresypkina, Eugenia V. ; Dütsch, Luis ; Seidl, Michael ; Balázs, Gabor ; Scheer, Manfred. / Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp₂Mo₂(CO)₄(η²-P₂)] Complex and Silver(I) Salts. In: European Journal of Inorganic Chemistry. 2017 ; Vol. 2017, No. 25. pp. 3222-3226.

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title = "Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp2Mo2(CO)4(η2-P2)] Complex and Silver(I) Salts",

abstract = "The reactions of the tetrahedral diphosphorus [Cp2Mo2(CO)4(η2-P2)] (1; Cp = C5H5) complex with Ag[Al{OC(CF3)3}4] (AgTEF) (A) and Ag[FAl{OC(C6F5)(C6F10)}3] (AgFAl) (B) were studied. The first reaction led to the formation of the [Ag2(η2-1)2(η1:η1-1)2][TEF]2 (2) dimer and the [Ag2(η1:η1-1)3]n[TEF]2n (3) coordination polymer, whereas the second reaction afforded the [Ag2(η1:η1-1)2(η1-CH2Cl2)2(η2-C7H8)2][FAl]2 (4) or the [Ag2(η2-1)2(η1:η1-1)2][FAl]2 (5) dimer and the [Ag2(η1:η1-1)4]n[FAl]2n (6) coordination polymer. In each case, the products obtained depended on the ratio of the reactants and/or the synthetic procedure.",

keywords = "Coordinating anions, Coordination polymers, Phosphorus, Silver, Synthetic methods, MOLECULE, LIGAND COMPLEXES, NMR-SPECTROSCOPY, BUILDING-BLOCKS, BEHAVIOR, ORGANIC HYBRID MATERIALS, ONE-DIMENSIONAL POLYMERS, FRAMEWORKS, PENTAPHOSPHAFERROCENE, CHEMISTRY",

author = "{Elsayed Moussa}, Mehdi and Martin Fleischmann and Peresypkina, {Eugenia V.} and Luis D{\"u}tsch and Michael Seidl and Gabor Bal{\'a}zs and Manfred Scheer",

year = "2017",

month = jul,

day = "7",

doi = "10.1002/ejic.201700646",

language = "English",

volume = "2017",

pages = "3222--3226",

journal = "European Journal of Inorganic Chemistry",

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Elsayed Moussa, M, Fleischmann, M, Peresypkina, EV, Dütsch, L, Seidl, M, Balázs, G & Scheer, M 2017, 'Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp₂Mo₂(CO)₄(η²-P₂)] Complex and Silver(I) Salts', European Journal of Inorganic Chemistry, vol. 2017, no. 25, pp. 3222-3226. https://doi.org/10.1002/ejic.201700646

Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp₂Mo₂(CO)₄(η²-P₂)] Complex and Silver(I) Salts. / Elsayed Moussa, Mehdi; Fleischmann, Martin; Peresypkina, Eugenia V.; Dütsch, Luis; Seidl, Michael; Balázs, Gabor; Scheer, Manfred.

In: European Journal of Inorganic Chemistry, Vol. 2017, No. 25, 07.07.2017, p. 3222-3226.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp2Mo2(CO)4(η2-P2)] Complex and Silver(I) Salts

AU - Elsayed Moussa, Mehdi

AU - Fleischmann, Martin

AU - Peresypkina, Eugenia V.

AU - Dütsch, Luis

AU - Seidl, Michael

AU - Balázs, Gabor

AU - Scheer, Manfred

PY - 2017/7/7

Y1 - 2017/7/7

N2 - The reactions of the tetrahedral diphosphorus [Cp2Mo2(CO)4(η2-P2)] (1; Cp = C5H5) complex with Ag[Al{OC(CF3)3}4] (AgTEF) (A) and Ag[FAl{OC(C6F5)(C6F10)}3] (AgFAl) (B) were studied. The first reaction led to the formation of the [Ag2(η2-1)2(η1:η1-1)2][TEF]2 (2) dimer and the [Ag2(η1:η1-1)3]n[TEF]2n (3) coordination polymer, whereas the second reaction afforded the [Ag2(η1:η1-1)2(η1-CH2Cl2)2(η2-C7H8)2][FAl]2 (4) or the [Ag2(η2-1)2(η1:η1-1)2][FAl]2 (5) dimer and the [Ag2(η1:η1-1)4]n[FAl]2n (6) coordination polymer. In each case, the products obtained depended on the ratio of the reactants and/or the synthetic procedure.

AB - The reactions of the tetrahedral diphosphorus [Cp2Mo2(CO)4(η2-P2)] (1; Cp = C5H5) complex with Ag[Al{OC(CF3)3}4] (AgTEF) (A) and Ag[FAl{OC(C6F5)(C6F10)}3] (AgFAl) (B) were studied. The first reaction led to the formation of the [Ag2(η2-1)2(η1:η1-1)2][TEF]2 (2) dimer and the [Ag2(η1:η1-1)3]n[TEF]2n (3) coordination polymer, whereas the second reaction afforded the [Ag2(η1:η1-1)2(η1-CH2Cl2)2(η2-C7H8)2][FAl]2 (4) or the [Ag2(η2-1)2(η1:η1-1)2][FAl]2 (5) dimer and the [Ag2(η1:η1-1)4]n[FAl]2n (6) coordination polymer. In each case, the products obtained depended on the ratio of the reactants and/or the synthetic procedure.

KW - Coordinating anions

KW - Coordination polymers

KW - Phosphorus

KW - Silver

KW - Synthetic methods

KW - MOLECULE

KW - LIGAND COMPLEXES

KW - NMR-SPECTROSCOPY

KW - BUILDING-BLOCKS

KW - BEHAVIOR

KW - ORGANIC HYBRID MATERIALS

KW - ONE-DIMENSIONAL POLYMERS

KW - FRAMEWORKS

KW - PENTAPHOSPHAFERROCENE

KW - CHEMISTRY

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U2 - 10.1002/ejic.201700646

DO - 10.1002/ejic.201700646

M3 - Article

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AN - SCOPUS:85024102591

VL - 2017

SP - 3222

EP - 3226

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

SN - 1434-1948

IS - 25

ER -

Elsayed Moussa M, Fleischmann M, Peresypkina EV, Dütsch L, Seidl M, Balázs G et al. Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp₂Mo₂(CO)₄(η²-P₂)] Complex and Silver(I) Salts. European Journal of Inorganic Chemistry. 2017 Jul 7;2017(25):3222-3226. https://doi.org/10.1002/ejic.201700646