Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp2Mo2(CO)42-P2)] Complex and Silver(I) Salts

Mehdi Elsayed Moussa, Martin Fleischmann, Eugenia V. Peresypkina, Luis Dütsch, Michael Seidl, Gabor Balázs, Manfred Scheer

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8 Citations (Scopus)

Abstract

The reactions of the tetrahedral diphosphorus [Cp2Mo2(CO)42-P2)] (1; Cp = C5H5) complex with Ag[Al{OC(CF3)3}4] (AgTEF) (A) and Ag[FAl{OC(C6F5)(C6F10)}3] (AgFAl) (B) were studied. The first reaction led to the formation of the [Ag22-1)211-1)2][TEF]2 (2) dimer and the [Ag211-1)3]n[TEF]2n (3) coordination polymer, whereas the second reaction afforded the [Ag211-1)21-CH2Cl2)22-C7H8)2][FAl]2 (4) or the [Ag22-1)211-1)2][FAl]2 (5) dimer and the [Ag211-1)4]n[FAl]2n (6) coordination polymer. In each case, the products obtained depended on the ratio of the reactants and/or the synthetic procedure.

Original languageEnglish
Pages (from-to)3222-3226
Number of pages5
JournalEuropean Journal of Inorganic Chemistry
Volume2017
Issue number25
DOIs
Publication statusPublished - 7 Jul 2017

Keywords

  • Coordinating anions
  • Coordination polymers
  • Phosphorus
  • Silver
  • Synthetic methods
  • MOLECULE
  • LIGAND COMPLEXES
  • NMR-SPECTROSCOPY
  • BUILDING-BLOCKS
  • BEHAVIOR
  • ORGANIC HYBRID MATERIALS
  • ONE-DIMENSIONAL POLYMERS
  • FRAMEWORKS
  • PENTAPHOSPHAFERROCENE
  • CHEMISTRY

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