Abstract
The reactions of the tetrahedral diphosphorus [Cp2Mo2(CO)4(η2-P2)] (1; Cp = C5H5) complex with Ag[Al{OC(CF3)3}4] (AgTEF) (A) and Ag[FAl{OC(C6F5)(C6F10)}3] (AgFAl) (B) were studied. The first reaction led to the formation of the [Ag2(η2-1)2(η1:η1-1)2][TEF]2 (2) dimer and the [Ag2(η1:η1-1)3]n[TEF]2n (3) coordination polymer, whereas the second reaction afforded the [Ag2(η1:η1-1)2(η1-CH2Cl2)2(η2-C7H8)2][FAl]2 (4) or the [Ag2(η2-1)2(η1:η1-1)2][FAl]2 (5) dimer and the [Ag2(η1:η1-1)4]n[FAl]2n (6) coordination polymer. In each case, the products obtained depended on the ratio of the reactants and/or the synthetic procedure.
Original language | English |
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Pages (from-to) | 3222-3226 |
Number of pages | 5 |
Journal | European Journal of Inorganic Chemistry |
Volume | 2017 |
Issue number | 25 |
DOIs | |
Publication status | Published - 7 Jul 2017 |
Keywords
- Coordinating anions
- Coordination polymers
- Phosphorus
- Silver
- Synthetic methods
- MOLECULE
- LIGAND COMPLEXES
- NMR-SPECTROSCOPY
- BUILDING-BLOCKS
- BEHAVIOR
- ORGANIC HYBRID MATERIALS
- ONE-DIMENSIONAL POLYMERS
- FRAMEWORKS
- PENTAPHOSPHAFERROCENE
- CHEMISTRY