Some Transformations of trans-Tetrapyridine Complexes of Nitrosoruthenium: Crystal Structures of [Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO and [H5O2]2[Ru(NO)Py4Cl]Cl4

A. N. Makhinya; M. A. Il’in; I. V. Korol’kov; I. A. Baidina

doi:10.1134/S1070328418100093

Some Transformations of trans-Tetrapyridine Complexes of Nitrosoruthenium: Crystal Structures of [Ru(NO)Py₄(OH)](PF₆)₂ ⋅ (CH₃)₂CO and [H₅O₂]₂[Ru(NO)Py₄Cl]Cl₄

A. N. Makhinya, M. A. Il’in, I. V. Korol’kov, I. A. Baidina

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Abstract

Abstract: The slow evaporation of an acetone solution containing trans-[Ru(NO)Py₄(OH)]²⁺ cations and hexafluorophosphate anions results in the crystallization of trans-[Ru(NO)Py₄(OH)](PF₆)₂ ⋅ (CH₃)₂CO (I). The reactions of trans‑[Ru(NO)Py₄(OH)]Cl₂ ⋅ H₂O with solutions of chloric or hydrochloric acid followed by the evaporation of the reaction solutions at ambient temperature afford trans-[Ru(NO)Py₄(H₂O)](ClO₄)₃ (II) or [H₅O₂]₂[Ru(NO)Py₄Cl]Cl₄ (III), respectively. The obtained chloride complex III is unstable and at ambient temperature eliminates hydrogen chloride to transform into trans-[Ru(NO)Py₄Cl]Cl₂ ⋅ 4H₂O (IV). The crystal structures of compounds I and III are determined by X-ray structure analysis (CIF files ССDC nos. 1421042 (I) and 1421041 (III)).

Original language	English
Pages (from-to)	613-618
Number of pages	6
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	44
Issue number	10
DOIs	https://doi.org/10.1134/S1070328418100093
Publication status	Published - 1 Oct 2018

Keywords

amino complexes
chloride complexes
hydroxo complexes
IR spectroscopy
nitrosoruthenium complexes
pyridine
X-ray structure analysis
LINKAGE ISOMERS
LIGHT
RUTHENIUM
INDUCED METASTABLE STATES

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@article{216f859e85ad49fca79436dd67d7fc9f,

title = "Some Transformations of trans-Tetrapyridine Complexes of Nitrosoruthenium: Crystal Structures of [Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO and [H5O2]2[Ru(NO)Py4Cl]Cl4",

abstract = "Abstract: The slow evaporation of an acetone solution containing trans-[Ru(NO)Py4(OH)]2+ cations and hexafluorophosphate anions results in the crystallization of trans-[Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO (I). The reactions of trans‑[Ru(NO)Py4(OH)]Cl2 ⋅ H2O with solutions of chloric or hydrochloric acid followed by the evaporation of the reaction solutions at ambient temperature afford trans-[Ru(NO)Py4(H2O)](ClO4)3 (II) or [H5O2]2[Ru(NO)Py4Cl]Cl4 (III), respectively. The obtained chloride complex III is unstable and at ambient temperature eliminates hydrogen chloride to transform into trans-[Ru(NO)Py4Cl]Cl2 ⋅ 4H2O (IV). The crystal structures of compounds I and III are determined by X-ray structure analysis (CIF files ССDC nos. 1421042 (I) and 1421041 (III)).",

keywords = "amino complexes, chloride complexes, hydroxo complexes, IR spectroscopy, nitrosoruthenium complexes, pyridine, X-ray structure analysis, LINKAGE ISOMERS, LIGHT, RUTHENIUM, INDUCED METASTABLE STATES",

author = "Makhinya, {A. N.} and Il{\textquoteright}in, {M. A.} and Korol{\textquoteright}kov, {I. V.} and Baidina, {I. A.}",

year = "2018",

month = oct,

day = "1",

doi = "10.1134/S1070328418100093",

language = "English",

volume = "44",

pages = "613--618",

journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

issn = "1070-3284",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "10",

}

Some Transformations of trans-Tetrapyridine Complexes of Nitrosoruthenium : Crystal Structures of [Ru(NO)Py₄(OH)](PF₆)₂ ⋅ (CH₃)₂CO and [H₅O₂]₂[Ru(NO)Py₄Cl]Cl₄. / Makhinya, A. N.; Il’in, M. A.; Korol’kov, I. V.; Baidina, I. A.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 44, No. 10, 01.10.2018, p. 613-618.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Some Transformations of trans-Tetrapyridine Complexes of Nitrosoruthenium

T2 - Crystal Structures of [Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO and [H5O2]2[Ru(NO)Py4Cl]Cl4

AU - Makhinya, A. N.

AU - Il’in, M. A.

AU - Korol’kov, I. V.

AU - Baidina, I. A.

PY - 2018/10/1

Y1 - 2018/10/1

N2 - Abstract: The slow evaporation of an acetone solution containing trans-[Ru(NO)Py4(OH)]2+ cations and hexafluorophosphate anions results in the crystallization of trans-[Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO (I). The reactions of trans‑[Ru(NO)Py4(OH)]Cl2 ⋅ H2O with solutions of chloric or hydrochloric acid followed by the evaporation of the reaction solutions at ambient temperature afford trans-[Ru(NO)Py4(H2O)](ClO4)3 (II) or [H5O2]2[Ru(NO)Py4Cl]Cl4 (III), respectively. The obtained chloride complex III is unstable and at ambient temperature eliminates hydrogen chloride to transform into trans-[Ru(NO)Py4Cl]Cl2 ⋅ 4H2O (IV). The crystal structures of compounds I and III are determined by X-ray structure analysis (CIF files ССDC nos. 1421042 (I) and 1421041 (III)).

AB - Abstract: The slow evaporation of an acetone solution containing trans-[Ru(NO)Py4(OH)]2+ cations and hexafluorophosphate anions results in the crystallization of trans-[Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO (I). The reactions of trans‑[Ru(NO)Py4(OH)]Cl2 ⋅ H2O with solutions of chloric or hydrochloric acid followed by the evaporation of the reaction solutions at ambient temperature afford trans-[Ru(NO)Py4(H2O)](ClO4)3 (II) or [H5O2]2[Ru(NO)Py4Cl]Cl4 (III), respectively. The obtained chloride complex III is unstable and at ambient temperature eliminates hydrogen chloride to transform into trans-[Ru(NO)Py4Cl]Cl2 ⋅ 4H2O (IV). The crystal structures of compounds I and III are determined by X-ray structure analysis (CIF files ССDC nos. 1421042 (I) and 1421041 (III)).

KW - amino complexes

KW - chloride complexes

KW - hydroxo complexes

KW - IR spectroscopy

KW - nitrosoruthenium complexes

KW - pyridine

KW - X-ray structure analysis

KW - LINKAGE ISOMERS

KW - LIGHT

KW - RUTHENIUM

KW - INDUCED METASTABLE STATES

UR - http://www.scopus.com/inward/record.url?scp=85054478295&partnerID=8YFLogxK

U2 - 10.1134/S1070328418100093

DO - 10.1134/S1070328418100093

M3 - Article

AN - SCOPUS:85054478295

VL - 44

SP - 613

EP - 618

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 10

ER -