Abstract
Abstract: The slow evaporation of an acetone solution containing trans-[Ru(NO)Py4(OH)]2+ cations and hexafluorophosphate anions results in the crystallization of trans-[Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO (I). The reactions of trans‑[Ru(NO)Py4(OH)]Cl2 ⋅ H2O with solutions of chloric or hydrochloric acid followed by the evaporation of the reaction solutions at ambient temperature afford trans-[Ru(NO)Py4(H2O)](ClO4)3 (II) or [H5O2]2[Ru(NO)Py4Cl]Cl4 (III), respectively. The obtained chloride complex III is unstable and at ambient temperature eliminates hydrogen chloride to transform into trans-[Ru(NO)Py4Cl]Cl2 ⋅ 4H2O (IV). The crystal structures of compounds I and III are determined by X-ray structure analysis (CIF files ССDC nos. 1421042 (I) and 1421041 (III)).
Original language | English |
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Pages (from-to) | 613-618 |
Number of pages | 6 |
Journal | Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya |
Volume | 44 |
Issue number | 10 |
DOIs | |
Publication status | Published - 1 Oct 2018 |
Keywords
- amino complexes
- chloride complexes
- hydroxo complexes
- IR spectroscopy
- nitrosoruthenium complexes
- pyridine
- X-ray structure analysis
- LINKAGE ISOMERS
- LIGHT
- RUTHENIUM
- INDUCED METASTABLE STATES