Simple synthetic protocol to obtain 3d-4f-heterometallic carboxylate complexes of N-heterocyclic carbenes

Stanislav A. Nikolaevskii, Pavel A. Petrov, Taisiya S. Sukhikh, Dmitriy S. Yambulatov, Mikhail A. Kiskin, Maxim N. Sokolov, Igor L. Eremenko

Research output: Contribution to journalArticle

Abstract

A new approach to NHC-substituted 3d-4f-heterometallic complexes is suggested based on coordination of the free NHC with a pre-organized carboxylate 3d-4f-core. Following this route, two novel complexes with different heterometallic cores, Co2La and Zn2Tb, have been prepared.

Original languageEnglish
Article number119643
Number of pages5
JournalInorganica Chimica Acta
Volume508
DOIs
Publication statusPublished - 1 Aug 2020

Keywords

  • Carboxylate complexes
  • Cobalt
  • Heterometallic complexes
  • Lanthanides
  • N-heterocyclic carbenes
  • Zinc
  • DEPROTONATION
  • PHOTOLUMINESCENCE
  • STEREOCHEMISTRY
  • REACTIVITY
  • HETEROMETALLIC COMPLEXES
  • LUMINESCENCE
  • CHEMISTRY
  • GENERATION
  • CATALYTIC-ACTIVITY
  • METAL-COMPLEXES

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