Rule, Not Exclusion: Formation of Dichlorine-Containing Supramolecular Complexes with Chlorometalates(IV)

Andrey N. Usoltsev, Nikita A. Korobeynikov, Boris A. Kolesov, Alexander S. Novikov, Denis G. Samsonenko, Vladimir P. Fedin, Maxim N. Sokolov, Sergey A. Adonin

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Abstract

Supramolecular derivatives of chlorostannate(IV) and -plumbate(IV) with {Cl2} units, Cat2{[MCl6](Cl2)x} (1-5; M = Sn, Pb, cat = 1-methylpyridinium (1-MePy), tetramethylammonium (TMA)) were prepared and characterized by X-ray diffractometry and Raman spectroscopy. In particular, the TMA-containing complexes demonstrate remarkable thermal stability, releasing Cl2 only at elevated temperatures.

Original languageEnglish
Pages (from-to)4171-4177
Number of pages7
JournalInorganic Chemistry
Volume60
Issue number6
DOIs
Publication statusPublished - 15 Mar 2021

OECD FOS+WOS

  • 1.04 CHEMICAL SCIENCES
  • 1.04.EI CHEMISTRY, PHYSICAL
  • 1.04.EC CHEMISTRY, INORGANIC & NUCLEAR

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