Room-Temperature Photogeneration of Nitrosyl Linkage Isomers in Ruthenium Nitrosyl Complexes

Artem A. Mikhailov, Emmanuel Wenger, Gennadiy A. Kostin, Dominik Schaniel

Research output: Contribution to journalArticlepeer-review

16 Citations (Scopus)

Abstract

The conditions for the photogeneration of NO linkage isomers at room temperature are studied. By pulsed laser irradiation in the blue spectral range, the long-lived Ru−ON isomer can be generated at room temperature, which is crucial for potential applications, such as holography and data storage. By using static and time-resolved spectroscopy (UV/Vis and IR), we give evidence that the liftime of the Ru−(η 2 -(NO)) isomer is a decisive parameter for the formation of the Ru−ON isomer at high temperature owing to a two-step isomerization mechanism Ru−NO→Ru−(η 2 -(NO))→Ru−ON. Furthermore, we report the low-temperature structures for each isomer, which were revealed by photocrystallography.

Original languageEnglish
Pages (from-to)7569-7574
Number of pages6
JournalChemistry - A European Journal
Volume25
Issue number31
DOIs
Publication statusPublished - 4 Jun 2019

Keywords

  • nitrosyl
  • photochemistry
  • photocrystallography
  • ruthenium
  • UV/Vis spectroscopy
  • MECHANISM
  • METASTABLE STATES

Fingerprint

Dive into the research topics of 'Room-Temperature Photogeneration of Nitrosyl Linkage Isomers in Ruthenium Nitrosyl Complexes'. Together they form a unique fingerprint.

Cite this