Redetermination of the crystal structure of the 2D heterometallic framework prepared from [Ni(cyclam)]2+ and [Re(CN)7]3-

Taisiya S. Sukhikh, Kira E. Vostrikova

Research output: Contribution to journalArticlepeer-review

Abstract

A new XRD experiment and crystal structure refinement was performed for the earlier published compound in the paper “Heterobimetallic coordination polymers involving 3d metal complexes and heavier transition metals cyanometallates” by Peresypkina et al. (2015) [1]. A choice of a crystal cell taking in consideration the superstructural reflections allowed to obtain more reliable data about the symmetry and bond distances in the heterometallic 2D framework {[Ni(cyclam)]2[ReO(OH)0.5(MeOH)0.5(CN)4]}2.5+. Additionally, doubling of the parameter c permitted to get more details about interlayer space. As a result, disordered perchlorate anions and solvate molecules were located.

Original languageEnglish
Pages (from-to)485-487
Number of pages3
JournalJournal of Solid State Chemistry
Volume258
DOIs
Publication statusPublished - 1 Feb 2018

Keywords

  • 2D coordination polymer
  • Crystal structure
  • Cyclam
  • Heptacyanorhenate
  • Nickel(II)
  • Rhenium

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