Reaction Operators for Radical Pairs. the Exactly Solvable Model

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Abstract

In the present work, the reaction operator for radical pairs of the main equation of spin chemistry has been modified on the basis of an exactly solvable model. The model contains both the reversible and irreversible transitions. For this model, expression for the reaction operator is more complex due to the expanded basis of spin states. The reaction operator of a phenomenological equation is a particular case of a more general approach and only in the limiting case of the completely irreversible recombination process, these operators coincide.

Original languageEnglish
Pages (from-to)225-238
Number of pages14
JournalZeitschrift fur Physikalische Chemie
Volume231
Issue number2
DOIs
Publication statusPublished - 1 Feb 2017

Keywords

  • basic equation
  • electron transfer
  • recombination
  • spin chemistry

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