Rare example of structurally characterized mononuclear N-heterocyclic carbene containing zinc carboxylate

Dmitriy S. Yambulatov, Pavel A. Petrov, Yulia V. Nelyubina, Alyona A. Starikova, Alexander A. Pavlov, Dmitry Yu Aleshin, Stanislav A. Nikolaevskii, Mikhail A. Kiskin, Maxim N. Sokolov, Igor L. Eremenko

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

An adduct of ZnII pivalate with N-heterocyclic carbene 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene has been prepared and characterized by X-ray diffraction analysis, NMR spectroscopy and DFT calculations. The compound preserves mononuclear structure in solution and does not switch the coordination mode from normal to abnormal.

Original languageEnglish
Pages (from-to)293-295
Number of pages3
JournalMendeleev Communications
Volume30
Issue number3
DOIs
Publication statusPublished - 1 May 2020

Keywords

  • carboxylate complexes
  • DFT calculations
  • N-heterocyclic carbenes
  • X-ray crystallography
  • zinc(II)

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