Radical polymerization of radical-labeled monomers: The triarylmethyl-based radical monomer as an example

Mariya V. Edeleva; Sylvain R.A. Marque; Olga Yu Rogozhnikova; Victor M. Tormyshev; Tatiana I. Troitskaya; Elena G. Bagryanskaya

doi:10.1002/pola.29249

Radical polymerization of radical-labeled monomers: The triarylmethyl-based radical monomer as an example

Mariya V. Edeleva, Sylvain R.A. Marque, Olga Yu Rogozhnikova, Victor M. Tormyshev, Tatiana I. Troitskaya, Elena G. Bagryanskaya

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Recent development of spin-labeled nitroxide-mediated polymerization (NMP) involving successful polymer preparation with high livingness and narrow dispersity in the presence of persistent trityl-based stable radicals attached to the initiators (90% recovery of a trityl radical signal after the polymerization) led us to the preparation of stable organic radical polymers based on trityl radical-substituted monomers using NMP as the method of polymerization despite the claims in the literature about its expected failure. Here, we present successful radical polymerization and NMP of a trityl radical-based tri- and mono-monomer yielding more than 90% recovery of the trityl radical signal.

Original language	English
Pages (from-to)	2656-2664
Number of pages	9
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	56
Issue number	23
DOIs	https://doi.org/10.1002/pola.29249
Publication status	Published - 1 Dec 2018

Keywords

kinetics of polymerization
nitroxide
stable organic radical
triarylmethyl radical
SYSTEM
NITROXIDE
BLOCK-COPOLYMERS
METHYL-METHACRYLATE
PHENYLAZOTRIPHENYLMETHANE
TRITYL RADICALS
COMBINATION
CHAIN TRANSFER
THERMAL INIFERTER
INITER PROCESS

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10.1002/pola.29249

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title = "Radical polymerization of radical-labeled monomers: The triarylmethyl-based radical monomer as an example",

abstract = "Recent development of spin-labeled nitroxide-mediated polymerization (NMP) involving successful polymer preparation with high livingness and narrow dispersity in the presence of persistent trityl-based stable radicals attached to the initiators (90% recovery of a trityl radical signal after the polymerization) led us to the preparation of stable organic radical polymers based on trityl radical-substituted monomers using NMP as the method of polymerization despite the claims in the literature about its expected failure. Here, we present successful radical polymerization and NMP of a trityl radical-based tri- and mono-monomer yielding more than 90% recovery of the trityl radical signal.",

keywords = "kinetics of polymerization, nitroxide, stable organic radical, triarylmethyl radical, SYSTEM, NITROXIDE, BLOCK-COPOLYMERS, METHYL-METHACRYLATE, PHENYLAZOTRIPHENYLMETHANE, TRITYL RADICALS, COMBINATION, CHAIN TRANSFER, THERMAL INIFERTER, INITER PROCESS",

author = "Edeleva, {Mariya V.} and Marque, {Sylvain R.A.} and Rogozhnikova, {Olga Yu} and Tormyshev, {Victor M.} and Troitskaya, {Tatiana I.} and Bagryanskaya, {Elena G.}",

year = "2018",

month = dec,

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doi = "10.1002/pola.29249",

language = "English",

volume = "56",

pages = "2656--2664",

journal = "Journal of Polymer Science, Part A: Polymer Chemistry",

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publisher = "John Wiley and Sons Inc.",

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Radical polymerization of radical-labeled monomers : The triarylmethyl-based radical monomer as an example. / Edeleva, Mariya V.; Marque, Sylvain R.A.; Rogozhnikova, Olga Yu; Tormyshev, Victor M.; Troitskaya, Tatiana I.; Bagryanskaya, Elena G.

In: Journal of Polymer Science, Part A: Polymer Chemistry, Vol. 56, No. 23, 01.12.2018, p. 2656-2664.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Radical polymerization of radical-labeled monomers

T2 - The triarylmethyl-based radical monomer as an example

AU - Edeleva, Mariya V.

AU - Marque, Sylvain R.A.

AU - Rogozhnikova, Olga Yu

AU - Tormyshev, Victor M.

AU - Troitskaya, Tatiana I.

AU - Bagryanskaya, Elena G.

PY - 2018/12/1

Y1 - 2018/12/1

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AB - Recent development of spin-labeled nitroxide-mediated polymerization (NMP) involving successful polymer preparation with high livingness and narrow dispersity in the presence of persistent trityl-based stable radicals attached to the initiators (90% recovery of a trityl radical signal after the polymerization) led us to the preparation of stable organic radical polymers based on trityl radical-substituted monomers using NMP as the method of polymerization despite the claims in the literature about its expected failure. Here, we present successful radical polymerization and NMP of a trityl radical-based tri- and mono-monomer yielding more than 90% recovery of the trityl radical signal.

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KW - stable organic radical

KW - triarylmethyl radical

KW - SYSTEM

KW - NITROXIDE

KW - BLOCK-COPOLYMERS

KW - METHYL-METHACRYLATE

KW - PHENYLAZOTRIPHENYLMETHANE

KW - TRITYL RADICALS

KW - COMBINATION

KW - CHAIN TRANSFER

KW - THERMAL INIFERTER

KW - INITER PROCESS

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EP - 2664

JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

SN - 0887-624X

IS - 23

ER -

Radical polymerization of radical-labeled monomers: The triarylmethyl-based radical monomer as an example

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Keywords

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