Polymeric Solids Based on [Re12CS14(μ-O)3(OH)6]6− Cluster and Alkaline Earth Metal Cations

Y. M. Gayfulin; A. I. Smolentsev; Y. V. Mironov

doi:10.1007/s10876-018-1374-6

Polymeric Solids Based on [Re₁₂CS₁₄(μ-O)₃(OH)₆]⁶⁻ Cluster and Alkaline Earth Metal Cations

Y. M. Gayfulin, A. I. Smolentsev, Y. V. Mironov

Polynuclear Coordination Compounds Laboratory

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The first study of the coordination ability of the [Re₁₂CS₁₄(μ-O)₃(OH)₆]⁶⁻ cluster anion was carried out using the cations of alkaline earth metals. Three new compounds displaying supramolecular structures were obtained based on Ca²⁺, Sr²⁺ and Ba²⁺ cations. Compounds K₄[M(H₂O)₇][Re₁₂CS₁₄(μ-O)₃(OH)₆]·15H₂O (M = Ca (1), Sr (2)) demonstrate the structures where disordered Ca²⁺ or Sr²⁺ aqua complexes, K⁺ ions and H₂O molecules are stabilized in the channels of anionic sub-lattice formed by cluster anions. Very short hydrogen bonds between the terminal OH⁻ ligands of the cluster anions are observed in these structures. Unlike Ca²⁺ and Sr²⁺, the Ba²⁺ cations are coordinated to the terminal OH-groups as well as to the μ-O²⁻ ligands of the cluster anion forming layered polymeric structure of compound [{Ba(H₂O)₄}{Ba(H₂O)₅}₂{Re₁₂CS₁₄(μ-O)₃(OH)₆}]·9H₂O (3).

Original language	English
Pages (from-to)	617-624
Number of pages	8
Journal	Journal of Cluster Science
Volume	29
Issue number	4
DOIs	https://doi.org/10.1007/s10876-018-1374-6
Publication status	Published - 1 Jul 2018

Keywords

Alkaline earth metal
Coordination polymer
Crystal structure
Rhenium cluster
DESIGN
HYDROGEN-BOND
STABILITY
COMPLEXES
COORDINATION
SUBSTITUTION-REACTIONS
CHEMISTRY
RHENIUM CLUSTERS
ORGANIC FRAMEWORKS
UNITS

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title = "Polymeric Solids Based on [Re12CS14(μ-O)3(OH)6]6− Cluster and Alkaline Earth Metal Cations",

abstract = "The first study of the coordination ability of the [Re12CS14(μ-O)3(OH)6]6− cluster anion was carried out using the cations of alkaline earth metals. Three new compounds displaying supramolecular structures were obtained based on Ca2+, Sr2+ and Ba2+ cations. Compounds K4[M(H2O)7][Re12CS14(μ-O)3(OH)6]·15H2O (M = Ca (1), Sr (2)) demonstrate the structures where disordered Ca2+ or Sr2+ aqua complexes, K+ ions and H2O molecules are stabilized in the channels of anionic sub-lattice formed by cluster anions. Very short hydrogen bonds between the terminal OH− ligands of the cluster anions are observed in these structures. Unlike Ca2+ and Sr2+, the Ba2+ cations are coordinated to the terminal OH-groups as well as to the μ-O2− ligands of the cluster anion forming layered polymeric structure of compound [{Ba(H2O)4}{Ba(H2O)5}2{Re12CS14(μ-O)3(OH)6}]·9H2O (3).",

keywords = "Alkaline earth metal, Coordination polymer, Crystal structure, Rhenium cluster, DESIGN, HYDROGEN-BOND, STABILITY, COMPLEXES, COORDINATION, SUBSTITUTION-REACTIONS, CHEMISTRY, RHENIUM CLUSTERS, ORGANIC FRAMEWORKS, UNITS",

author = "Gayfulin, {Y. M.} and Smolentsev, {A. I.} and Mironov, {Y. V.}",

year = "2018",

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doi = "10.1007/s10876-018-1374-6",

language = "English",

volume = "29",

pages = "617--624",

journal = "Journal of Cluster Science",

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publisher = "Springer New York",

number = "4",

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TY - JOUR

T1 - Polymeric Solids Based on [Re12CS14(μ-O)3(OH)6]6− Cluster and Alkaline Earth Metal Cations

AU - Gayfulin, Y. M.

AU - Smolentsev, A. I.

AU - Mironov, Y. V.

PY - 2018/7/1

Y1 - 2018/7/1

N2 - The first study of the coordination ability of the [Re12CS14(μ-O)3(OH)6]6− cluster anion was carried out using the cations of alkaline earth metals. Three new compounds displaying supramolecular structures were obtained based on Ca2+, Sr2+ and Ba2+ cations. Compounds K4[M(H2O)7][Re12CS14(μ-O)3(OH)6]·15H2O (M = Ca (1), Sr (2)) demonstrate the structures where disordered Ca2+ or Sr2+ aqua complexes, K+ ions and H2O molecules are stabilized in the channels of anionic sub-lattice formed by cluster anions. Very short hydrogen bonds between the terminal OH− ligands of the cluster anions are observed in these structures. Unlike Ca2+ and Sr2+, the Ba2+ cations are coordinated to the terminal OH-groups as well as to the μ-O2− ligands of the cluster anion forming layered polymeric structure of compound [{Ba(H2O)4}{Ba(H2O)5}2{Re12CS14(μ-O)3(OH)6}]·9H2O (3).

AB - The first study of the coordination ability of the [Re12CS14(μ-O)3(OH)6]6− cluster anion was carried out using the cations of alkaline earth metals. Three new compounds displaying supramolecular structures were obtained based on Ca2+, Sr2+ and Ba2+ cations. Compounds K4[M(H2O)7][Re12CS14(μ-O)3(OH)6]·15H2O (M = Ca (1), Sr (2)) demonstrate the structures where disordered Ca2+ or Sr2+ aqua complexes, K+ ions and H2O molecules are stabilized in the channels of anionic sub-lattice formed by cluster anions. Very short hydrogen bonds between the terminal OH− ligands of the cluster anions are observed in these structures. Unlike Ca2+ and Sr2+, the Ba2+ cations are coordinated to the terminal OH-groups as well as to the μ-O2− ligands of the cluster anion forming layered polymeric structure of compound [{Ba(H2O)4}{Ba(H2O)5}2{Re12CS14(μ-O)3(OH)6}]·9H2O (3).

KW - Alkaline earth metal

KW - Coordination polymer

KW - Crystal structure

KW - Rhenium cluster

KW - DESIGN

KW - HYDROGEN-BOND

KW - STABILITY

KW - COMPLEXES

KW - COORDINATION

KW - SUBSTITUTION-REACTIONS

KW - CHEMISTRY

KW - RHENIUM CLUSTERS

KW - ORGANIC FRAMEWORKS

KW - UNITS

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U2 - 10.1007/s10876-018-1374-6

DO - 10.1007/s10876-018-1374-6

M3 - Article

AN - SCOPUS:85045834828

VL - 29

SP - 617

EP - 624

JO - Journal of Cluster Science

JF - Journal of Cluster Science

SN - 1040-7278

IS - 4

ER -

Polymeric Solids Based on [Re₁₂CS₁₄(μ-O)₃(OH)₆]⁶⁻ Cluster and Alkaline Earth Metal Cations

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Keywords

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