Polymeric Lead(II) Iodoacetate: Pb···I and I···I Non-Covalent Interactions in the Solid State

Sergey A. Adonin, Alexander S. Novikov, Maxim N. Sokolov

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Two-dimensional Pb II iodoacetate complex {Pb(ICH 2 COO) 2 } n (1) was prepared by reaction of lead nitrate with potassium iodoacetate. In 1, Pb is hepta-coordinated; additionally, metal centers participate in non-covalent I···I and Pb···I contacts. According to the analysis of XRD data and DFT calculations, the I···I non-covalent interactions are crystal packing-induced type I contacts, and Pb···I contacts are caused by interactions between Pb 2+ as electrophilic center and lone pairs of the iodine atom.

Original languageEnglish
Pages (from-to)4221-4223
Number of pages3
JournalEuropean Journal of Inorganic Chemistry
Volume2019
Issue number39-40
DOIs
Publication statusPublished - 31 Oct 2019

Keywords

  • Coordination polymers
  • Iodoacetate
  • Lead
  • Noncovalent interactions
  • QTAIM
  • ANIONS
  • INTERPLAY
  • ORGANIC-LIGANDS
  • NICKEL(II)
  • HETEROMETALLIC COMPLEXES
  • HYDROGEN
  • HALOGEN BONDING INTERACTIONS
  • CRYSTALS
  • METAL-IONS
  • ARCHITECTURES

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