Polymeric Lead(II) Iodoacetate: Pb···I and I···I Non-Covalent Interactions in the Solid State

Sergey A. Adonin; Alexander S. Novikov; Maxim N. Sokolov

doi:10.1002/ejic.201900349

Polymeric Lead(II) Iodoacetate: Pb···I and I···I Non-Covalent Interactions in the Solid State

Sergey A. Adonin, Alexander S. Novikov, Maxim N. Sokolov

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Two-dimensional Pb ^II iodoacetate complex {Pb(ICH ₂ COO) ₂ } _n (1) was prepared by reaction of lead nitrate with potassium iodoacetate. In 1, Pb is hepta-coordinated; additionally, metal centers participate in non-covalent I···I and Pb···I contacts. According to the analysis of XRD data and DFT calculations, the I···I non-covalent interactions are crystal packing-induced type I contacts, and Pb···I contacts are caused by interactions between Pb ²⁺ as electrophilic center and lone pairs of the iodine atom.

Original language	English
Pages (from-to)	4221-4223
Number of pages	3
Journal	European Journal of Inorganic Chemistry
Volume	2019
Issue number	39-40
DOIs	https://doi.org/10.1002/ejic.201900349
Publication status	Published - 31 Oct 2019

Keywords

Coordination polymers
Iodoacetate
Lead
Noncovalent interactions
QTAIM
ANIONS
INTERPLAY
ORGANIC-LIGANDS
NICKEL(II)
HETEROMETALLIC COMPLEXES
HYDROGEN
HALOGEN BONDING INTERACTIONS
CRYSTALS
METAL-IONS
ARCHITECTURES

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10.1002/ejic.201900349

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title = "Polymeric Lead(II) Iodoacetate: Pb···I and I···I Non-Covalent Interactions in the Solid State",

abstract = " Two-dimensional Pb II iodoacetate complex {Pb(ICH 2 COO) 2 } n (1) was prepared by reaction of lead nitrate with potassium iodoacetate. In 1, Pb is hepta-coordinated; additionally, metal centers participate in non-covalent I···I and Pb···I contacts. According to the analysis of XRD data and DFT calculations, the I···I non-covalent interactions are crystal packing-induced type I contacts, and Pb···I contacts are caused by interactions between Pb 2+ as electrophilic center and lone pairs of the iodine atom. ",

keywords = "Coordination polymers, Iodoacetate, Lead, Noncovalent interactions, QTAIM, ANIONS, INTERPLAY, ORGANIC-LIGANDS, NICKEL(II), HETEROMETALLIC COMPLEXES, HYDROGEN, HALOGEN BONDING INTERACTIONS, CRYSTALS, METAL-IONS, ARCHITECTURES",

author = "Adonin, {Sergey A.} and Novikov, {Alexander S.} and Sokolov, {Maxim N.}",

year = "2019",

month = oct,

day = "31",

doi = "10.1002/ejic.201900349",

language = "English",

volume = "2019",

pages = "4221--4223",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

number = "39-40",

}

TY - JOUR

T1 - Polymeric Lead(II) Iodoacetate

T2 - Pb···I and I···I Non-Covalent Interactions in the Solid State

AU - Adonin, Sergey A.

AU - Novikov, Alexander S.

AU - Sokolov, Maxim N.

PY - 2019/10/31

Y1 - 2019/10/31

N2 - Two-dimensional Pb II iodoacetate complex {Pb(ICH 2 COO) 2 } n (1) was prepared by reaction of lead nitrate with potassium iodoacetate. In 1, Pb is hepta-coordinated; additionally, metal centers participate in non-covalent I···I and Pb···I contacts. According to the analysis of XRD data and DFT calculations, the I···I non-covalent interactions are crystal packing-induced type I contacts, and Pb···I contacts are caused by interactions between Pb 2+ as electrophilic center and lone pairs of the iodine atom.

AB - Two-dimensional Pb II iodoacetate complex {Pb(ICH 2 COO) 2 } n (1) was prepared by reaction of lead nitrate with potassium iodoacetate. In 1, Pb is hepta-coordinated; additionally, metal centers participate in non-covalent I···I and Pb···I contacts. According to the analysis of XRD data and DFT calculations, the I···I non-covalent interactions are crystal packing-induced type I contacts, and Pb···I contacts are caused by interactions between Pb 2+ as electrophilic center and lone pairs of the iodine atom.

KW - Coordination polymers

KW - Iodoacetate

KW - Lead

KW - Noncovalent interactions

KW - QTAIM

KW - ANIONS

KW - INTERPLAY

KW - ORGANIC-LIGANDS

KW - NICKEL(II)

KW - HETEROMETALLIC COMPLEXES

KW - HYDROGEN

KW - HALOGEN BONDING INTERACTIONS

KW - CRYSTALS

KW - METAL-IONS

KW - ARCHITECTURES

UR - http://www.scopus.com/inward/record.url?scp=85065675492&partnerID=8YFLogxK

U2 - 10.1002/ejic.201900349

DO - 10.1002/ejic.201900349

M3 - Article

AN - SCOPUS:85065675492

VL - 2019

SP - 4221

EP - 4223

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

SN - 1434-1948

IS - 39-40

ER -

Polymeric Lead(II) Iodoacetate: Pb···I and I···I Non-Covalent Interactions in the Solid State

Abstract

Keywords

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