Abstract
Two-dimensional Pb II iodoacetate complex {Pb(ICH 2 COO) 2 } n (1) was prepared by reaction of lead nitrate with potassium iodoacetate. In 1, Pb is hepta-coordinated; additionally, metal centers participate in non-covalent I···I and Pb···I contacts. According to the analysis of XRD data and DFT calculations, the I···I non-covalent interactions are crystal packing-induced type I contacts, and Pb···I contacts are caused by interactions between Pb 2+ as electrophilic center and lone pairs of the iodine atom.
Original language | English |
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Pages (from-to) | 4221-4223 |
Number of pages | 3 |
Journal | European Journal of Inorganic Chemistry |
Volume | 2019 |
Issue number | 39-40 |
DOIs | |
Publication status | Published - 31 Oct 2019 |
Keywords
- Coordination polymers
- Iodoacetate
- Lead
- Noncovalent interactions
- QTAIM
- ANIONS
- INTERPLAY
- ORGANIC-LIGANDS
- NICKEL(II)
- HETEROMETALLIC COMPLEXES
- HYDROGEN
- HALOGEN BONDING INTERACTIONS
- CRYSTALS
- METAL-IONS
- ARCHITECTURES