Polymeric hybrid iodoplumbates and iodobismuthates containing mono- and bisalkylated derivatives of 1,2-bis(4-pyridyl)ethylene: Structural and optical features

Andrey N. Usoltsev, Sergey A. Adonin, Pavel A. Abramov, Ilya V. Korolkov, Irina V. Yushina, Olga V. Antonova, Maxim N. Sokolov, Vladimir P. Fedin

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Abstract

Reactions of PbI2 with N-alkylated derivatives of 1,2-bis(4-pyridyl)ethylene (bpen) MeBpenI and Me2BpenI2 result in 1D-polymeric complexes [{Pb(MeBpen)I3}] (1) and (Me2bpen)[{PbI3}]2 (2). For both compounds, band gap values were determinated experimentally; 1 demonstrates weak red luminescence. Binuclear hybrid iodobismuthate [Bi2(MeBpen)2I8] (3) was obtained by the similar scheme using BiI3 instead of PbI2.

Original languageEnglish
Pages (from-to)323-328
Number of pages6
JournalInorganica Chimica Acta
Volume462
DOIs
Publication statusPublished - 1 Jun 2017

Keywords

  • Band gap determination
  • Bismuth
  • Iodide complexes
  • Lead
  • Luminescence
  • X-ray diffractometry
  • PHOTOCATALYTIC PROPERTIES
  • SOLAR-CELLS
  • LEAD-FREE
  • BISMUTH COMPLEXES
  • CRYSTAL-STRUCTURES
  • ORGANIC-INORGANIC HYBRID
  • LAYERED PEROVSKITE SEMICONDUCTOR
  • CENTER-DOT
  • COORDINATION POLYMERS
  • HIRSHFELD SURFACE

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