Polyhalide-bonded metal complexes: Structural diversity in an eclectic class of compounds

Sergey A. Adonin; Maxim N. Sokolov; Vladimir P. Fedin

doi:10.1016/j.ccr.2018.04.010

Polyhalide-bonded metal complexes: Structural diversity in an eclectic class of compounds

Sergey A. Adonin, Maxim N. Sokolov, Vladimir P. Fedin

Research output: Contribution to journal › Review article › peer-review

22 Citations (Scopus)

Abstract

This review is focused on a special class of metal complexes where polyhalide units are either coordinated to metal (“true polyhalide complexes”) or form specific associates with metal center via halogen⋯halogen contacts. Diversity of structural types, as well as main characterization features, is discussed for all d-elements and p-block metals and metalloids, providing a concentrated source of information on this eclectic class of compounds.

Original language	English
Pages (from-to)	1-17
Number of pages	17
Journal	Coordination Chemistry Reviews
Volume	367
DOIs	https://doi.org/10.1016/j.ccr.2018.04.010
Publication status	Published - 15 Jul 2018

Keywords

Halide complexes
Halogen bonding
Polyhalides
Supramolecular interactions
PHENYLTRIMETHYLAMMONIUM SALTS
MOLECULAR-STRUCTURE
COORDINATION-POLYMER
POLYIODIDE NETWORKS
TEMPERATURE IONIC LIQUID
HALOGEN-HALOGEN INTERACTIONS
RAY CRYSTAL-STRUCTURES
CENTER-DOT 2I(2)
X-RAY
OXIDATIVE-ADDITION

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10.1016/j.ccr.2018.04.010

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title = "Polyhalide-bonded metal complexes: Structural diversity in an eclectic class of compounds",

abstract = "This review is focused on a special class of metal complexes where polyhalide units are either coordinated to metal (“true polyhalide complexes”) or form specific associates with metal center via halogen⋯halogen contacts. Diversity of structural types, as well as main characterization features, is discussed for all d-elements and p-block metals and metalloids, providing a concentrated source of information on this eclectic class of compounds.",

keywords = "Halide complexes, Halogen bonding, Polyhalides, Supramolecular interactions, PHENYLTRIMETHYLAMMONIUM SALTS, MOLECULAR-STRUCTURE, COORDINATION-POLYMER, POLYIODIDE NETWORKS, TEMPERATURE IONIC LIQUID, HALOGEN-HALOGEN INTERACTIONS, RAY CRYSTAL-STRUCTURES, CENTER-DOT 2I(2), X-RAY, OXIDATIVE-ADDITION",

author = "Adonin, {Sergey A.} and Sokolov, {Maxim N.} and Fedin, {Vladimir P.}",

year = "2018",

month = jul,

day = "15",

doi = "10.1016/j.ccr.2018.04.010",

language = "English",

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journal = "Coordination Chemistry Reviews",

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T1 - Polyhalide-bonded metal complexes

T2 - Structural diversity in an eclectic class of compounds

AU - Adonin, Sergey A.

AU - Sokolov, Maxim N.

AU - Fedin, Vladimir P.

PY - 2018/7/15

Y1 - 2018/7/15

N2 - This review is focused on a special class of metal complexes where polyhalide units are either coordinated to metal (“true polyhalide complexes”) or form specific associates with metal center via halogen⋯halogen contacts. Diversity of structural types, as well as main characterization features, is discussed for all d-elements and p-block metals and metalloids, providing a concentrated source of information on this eclectic class of compounds.

AB - This review is focused on a special class of metal complexes where polyhalide units are either coordinated to metal (“true polyhalide complexes”) or form specific associates with metal center via halogen⋯halogen contacts. Diversity of structural types, as well as main characterization features, is discussed for all d-elements and p-block metals and metalloids, providing a concentrated source of information on this eclectic class of compounds.

KW - Halide complexes

KW - Halogen bonding

KW - Polyhalides

KW - Supramolecular interactions

KW - PHENYLTRIMETHYLAMMONIUM SALTS

KW - MOLECULAR-STRUCTURE

KW - COORDINATION-POLYMER

KW - POLYIODIDE NETWORKS

KW - TEMPERATURE IONIC LIQUID

KW - HALOGEN-HALOGEN INTERACTIONS

KW - RAY CRYSTAL-STRUCTURES

KW - CENTER-DOT 2I(2)

KW - X-RAY

KW - OXIDATIVE-ADDITION

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U2 - 10.1016/j.ccr.2018.04.010

DO - 10.1016/j.ccr.2018.04.010

M3 - Review article

AN - SCOPUS:85045555163

VL - 367

SP - 1

EP - 17

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

SN - 0010-8545

ER -

Polyhalide-bonded metal complexes: Structural diversity in an eclectic class of compounds

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Keywords

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