Abstract
This review is focused on a special class of metal complexes where polyhalide units are either coordinated to metal (“true polyhalide complexes”) or form specific associates with metal center via halogen⋯halogen contacts. Diversity of structural types, as well as main characterization features, is discussed for all d-elements and p-block metals and metalloids, providing a concentrated source of information on this eclectic class of compounds.
Original language | English |
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Pages (from-to) | 1-17 |
Number of pages | 17 |
Journal | Coordination Chemistry Reviews |
Volume | 367 |
DOIs | |
Publication status | Published - 15 Jul 2018 |
Keywords
- Halide complexes
- Halogen bonding
- Polyhalides
- Supramolecular interactions
- PHENYLTRIMETHYLAMMONIUM SALTS
- MOLECULAR-STRUCTURE
- COORDINATION-POLYMER
- POLYIODIDE NETWORKS
- TEMPERATURE IONIC LIQUID
- HALOGEN-HALOGEN INTERACTIONS
- RAY CRYSTAL-STRUCTURES
- CENTER-DOT 2I(2)
- X-RAY
- OXIDATIVE-ADDITION