Polybromide salts of tetraalkyl and N-heterocyclic cations: New entries into the structural library

Igor D. Gorokh, Sergey A. Adonin, Maxim N. Sokolov, Pavel A. Abramov, Ilya V. Korolkov, Evgeniy Yu Semitut, Vladimir P. Fedin

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

Reactions between Br2 dissolved in HBr and salts of various organic cations resulted in formation of a series of polyhalide salts: (IsoquinolH)Br3 (1), (2-BrPyH)Br3 (2), (H2(4,4′-bipy))(Br3)2 (3), Bu4NBr3 (4), (Collidinium){(Br3)(Br2)} (5) and Et4N{(Br3)(Br2)2} (6). All compounds were characterized by X-ray diffractometry; the role of supramolecular Br⋯Br contacts is discussed.

Original languageEnglish
Pages (from-to)583-587
Number of pages5
JournalInorganica Chimica Acta
Volume469
DOIs
Publication statusPublished - 1 Jan 2018

Keywords

  • Polybromides
  • Polyhalides
  • Supramolecular contacts
  • X-ray diffractometry
  • ANIONS
  • NETWORK
  • CRYSTAL-STRUCTURES
  • FLOW BATTERY
  • HALOGEN-HALOGEN INTERACTIONS
  • QUATERNARY AMMONIUM
  • TRIBROMIDE
  • BROMINE
  • IONIC LIQUIDS
  • DIHALOGENS

Fingerprint

Dive into the research topics of 'Polybromide salts of tetraalkyl and N-heterocyclic cations: New entries into the structural library'. Together they form a unique fingerprint.

Cite this