Paramagnetic Rhenium Iodide Cluster with N-Heterocyclic Carbene

Pavel A. Petrov, Taisiya S. Sukhikh, Vladimir A. Nadolinny, Maxim A. Mikhaylov, Alexander N. Lavrov, Alexey A. Dmitriev, Nina P. Gritsan, Maxim N. Sokolov

Research output: Contribution to journalArticlepeer-review

Abstract

triangulo-Trirhenium nonaiodide Re3I9 reacts with 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes) to produce the novel 13-electron paramagnetic cluster Re3I8(IMes)2, which was characterized by means of X-ray diffraction analysis, ESR spectroscopy, magnetometry, and quantum chemistry.

Original languageEnglish
Pages (from-to)6746-6752
Number of pages7
JournalInorganic Chemistry
Volume60
Issue number9
DOIs
Publication statusPublished - 3 May 2021

OECD FOS+WOS

  • 1.04 CHEMICAL SCIENCES

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