Organometallic–Organic Hybrid Polymers Assembled from Pentaphosphaferrocene, Bipyridyl Linkers, and CuI Ions

Mehdi Elsayed Moussa, Stefan Welsch, Matthias Lochner, Eugenia V. Peresypkina, Alexander V. Virovets, Manfred Scheer

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

A multicomponent approach of the Pn ligand complex [Cp*Fe(η5-P5)] (1: Cp* = η5-C5Me5) with the ditopic organic linkers 4,4′-bipyridine (2) or trans-1,2-di(pyridine-4-yl)ethene (3) in the presence of CuI salts of the anions [BF4] and [PF6] or the coordinating anion Br, leads to the formation of four novel organometallic–organic hybrid polymers: the cationic 1D polymeric compounds [Cu4{Cp*Fe(µ35:1:1-P5)}2(µ,η1:1-C10H8N2)4(CH3CN)4]n[BF4]4n (4) and [Cu4{Cp*Fe(µ35:1:1-P5)}2(µ,η1:1-C10H8N2)4(CH3CN)4]n[PF6]4n (5) as well as the unique neutral threefold 2D → 2D interpenetrated networks [Cu2Cl2{Cp*Fe(µ35:1:1-P5)}(µ,η1:1-C12H10N2)]n (6) and [Cu2Br2{Cp*Fe(µ35:1:1-P5)}(µ,η1:1-C10H8N2)]n (7).

Original languageEnglish
Pages (from-to)2689-2694
Number of pages6
JournalEuropean Journal of Inorganic Chemistry
Volume2018
Issue number23
DOIs
Publication statusPublished - 22 Jun 2018

Keywords

  • Coordination modes
  • Copper
  • Ferrocene ligands
  • Hybrid polymers
  • Ligand effects
  • BUILDING-BLOCKS
  • CRYSTAL-STRUCTURES
  • NETWORKS
  • LIGAND COMPLEX
  • 2D
  • ABSTRACTION
  • DIPHOSPHORUS COMPLEX
  • SUPRAMOLECULE
  • COORDINATION POLYMERS
  • DICHLOROMETHANE

Fingerprint Dive into the research topics of 'Organometallic–Organic Hybrid Polymers Assembled from Pentaphosphaferrocene, Bipyridyl Linkers, and Cu<sup>I</sup> Ions'. Together they form a unique fingerprint.

Cite this