One-step synthesis of tetrahedral rhenium chalcocyanide cluster complexes [{Re43-Q)4}(CN)12]4− (Q = S, Se, Te) using ReI3

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Abstract

A new method is proposed for the one-step synthesis of tetrahedral rhenium chalcocyanide cluster complexes [{Re43-Q)4}(CN)12]4− (Q = S, Se, Te) using rhenium(iii) iodide as the starting compound. A cluster complex of the composition K4[{Re4S4}(CN)12]•H2O was synthesized for the first time and characterized by X-ray diffraction.

Original languageEnglish
Pages (from-to)777-781
Number of pages5
JournalRussian Chemical Bulletin
Volume68
Issue number4
DOIs
Publication statusPublished - 1 Apr 2019

Keywords

  • chalcogen
  • crystal structure
  • rhenium
  • tetrahedral cluster complexes
  • CRYSTAL-STRUCTURE

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