One-Dimensional Supramolecular Hybrid Iodobismuthate (1-EtPy)3{[Bi2I9](I2)0.75}: Structural Features and Theoretical Studies of I···I Non-Covalent Interactions

Andrey N. Usoltsev, Nikita A. Korobeynikov, Alexander S. Novikov, Vladimir R. Shayapov, Ilya V. Korolkov, Denis G. Samsonenko, Vladimir P. Fedin, Maxim N. Sokolov, Sergey A. Adonin

Research output: Contribution to journalArticlepeer-review

Abstract

In supramolecular complex (1-EtPy)3{[Bi2I9](I2)0.75} (1), diiodine fragments are “captured” by iodobismuthate anions via the system of non-covalent I···I interactions (halogen bonding). The energies of latter were estimated by theoretical methods; optical features and Raman spectrum are discussed.

Original languageEnglish
Number of pages5
JournalJournal of Cluster Science
DOIs
Publication statusPublished - 30 Jun 2020

Keywords

  • Bismuth
  • Halide complexes
  • Halogen bonding
  • Iodine
  • Non-covalent interactions
  • CRYSTAL-STRUCTURE
  • RAMAN-SPECTROSCOPY
  • IODIDE
  • OPTICAL-PROPERTIES
  • HALIDE-COMPLEXES
  • THERMOCHROMIC PROPERTIES
  • METHYLAMMONIUM LEAD
  • LUMINESCENCE
  • FERROELECTRIC BIS(IMIDAZOLIUM) PENTACHLOROANTIMONATE(III)
  • BOND

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