One-Dimensional Supramolecular Hybrid Iodobismuthate (1-EtPy)3{[Bi2I9](I2)0.75}: Structural Features and Theoretical Studies of I···I Non-Covalent Interactions

Andrey N. Usoltsev, Nikita A. Korobeynikov, Alexander S. Novikov, Vladimir R. Shayapov, Ilya V. Korolkov, Denis G. Samsonenko, Vladimir P. Fedin, Maxim N. Sokolov, Sergey A. Adonin

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1 Citation (Scopus)

Abstract

In supramolecular complex (1-EtPy)3{[Bi2I9](I2)0.75} (1), diiodine fragments are “captured” by iodobismuthate anions via the system of non-covalent I···I interactions (halogen bonding). The energies of latter were estimated by theoretical methods; optical features and Raman spectrum are discussed.

Original languageEnglish
Pages (from-to)787-791
Number of pages5
JournalJournal of Cluster Science
Volume32
Issue number3
DOIs
Publication statusPublished - May 2021

Keywords

  • Bismuth
  • Halide complexes
  • Halogen bonding
  • Iodine
  • Non-covalent interactions
  • CRYSTAL-STRUCTURE
  • RAMAN-SPECTROSCOPY
  • IODIDE
  • OPTICAL-PROPERTIES
  • HALIDE-COMPLEXES
  • THERMOCHROMIC PROPERTIES
  • METHYLAMMONIUM LEAD
  • LUMINESCENCE
  • FERROELECTRIC BIS(IMIDAZOLIUM) PENTACHLOROANTIMONATE(III)
  • BOND

OECD FOS+WOS

  • 1.04 CHEMICAL SCIENCES

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