On the Way Towards Fine Inorganic Synthesis: Manipulating Bridging Ligands in Chalcogenide Clusters

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Abstract

Abstract: This review describes approaches to the targeted multistep synthesis of coordination compounds exemplified by Group 5 and 6 metal chalcogenide and oxide clusters and polynuclear compounds. Methods for the introduction of two different chalcogen atoms and methods for the synthesis of mixed oxide chalcogenide complexes are considered.

Original languageEnglish
Pages (from-to)385-401
Number of pages17
JournalRussian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume45
Issue number6
DOIs
Publication statusPublished - 1 Jun 2019

Keywords

  • clusters and polynuclear compounds
  • inorganic synthesis
  • polyoxometallates
  • transition metals
  • MO
  • X-RAY-STRUCTURE
  • COMPLEXES
  • CARBONYL-COMPOUNDS
  • STRUCTURAL-CHARACTERIZATION
  • SULFUR
  • LINKAGE ISOMERISM
  • TRIANGULAR CLUSTER
  • AQUA ION
  • MOLYBDENUM CLUSTERS

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