Octafluorobiphenyl-4,4′-dicarboxylate as a ligand for metal-organic frameworks: Progress and perspectives

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Abstract

While metal-organic frameworks based on aromatic carboxylates are very numerous and well investigated, the chemistry of their fully fluorinated analogues is at the very beginning. This minireview aims at summarizing all metal complexes with octafluorobiphenyl-4,4′-dicarboxylate (oFBPDC2-) anion and in particular, porous coordination polymers, their syntheses, crystal structures and functional properties highlighting the importance of further investigation of such systems.

Original languageEnglish
Pages (from-to)1081-1092
Number of pages12
JournalPure and Applied Chemistry
Volume92
Issue number7
DOIs
Publication statusPublished - 1 Jul 2020

Keywords

  • gas sorption
  • hydrophobicity
  • Mendeleev-21
  • metal-organic frameworks
  • perfluorinated ligands
  • photoluminescence
  • DESIGN
  • ACID
  • CRYSTAL-STRUCTURE
  • STABILITY
  • COMPLEXES
  • UIO-66
  • ADSORPTION
  • FUNCTIONALIZATION
  • PRESSURE
  • PADDLE-WHEEL
  • Perfluorinated ligands
  • Photoluminescence
  • Gas sorption
  • Hydrophobicity
  • Metal-organic frameworks

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