Novel molybdenum complexes with the 3,6-Di-tert-butylcatecholate ligand

P. A. Petrov, M. Yu Afonin, D. Yu Naumov, S. N. Konchenko, A. V. Piskunov

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

A reaction of the cluster (Et4N)2[Mo3S7Br6] with potassium 3,6-di-tert-butyl-o-benzosemiquinolate (KSQ36) afforded the mononuclear complexes (Et4N)[Mo(Cat36)3] (I) and (Et4N)[MoO(Cat36)2(HCat36)] (II) with prismatic and octahedral environments of their central metal atoms, respectively. Complex I was also obtained by a reaction between MoCl5, sodium 3,6-di-tert-butylcatecholate (Na2Cat36), and Et4NBr. Complexes I and II were characterized by X-ray diffraction and EPR spectroscopy. The structures have been deposited with the Cambridge Structural Database (nos. 1009139 (I), 1009140 (I · 1.5THF), and 1009141 (II · Et2O)).

Original languageEnglish
Pages (from-to)31-36
Number of pages6
JournalRussian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume41
Issue number1
DOIs
Publication statusPublished - 1 Jan 2015

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