Nonstoichiometry in the systems Na2MoO4–MMoO4 (M = Co, Cd), crystal structures of Na3.36Co1.32(MoO4)3, Na3.13Mn1.43(MoO4)3 and Na3.72Cd1.14(MoO4)3, crystal chemistry, compositions and ionic conductivity of alluaudite-type double molybdates and tungstates

Sergey F. Solodovnikov; Zoya A. Solodovnikova; Evgeniya S. Zolotova; Vasiliy N. Yudin; Oksana A. Gulyaeva; Yunna L. Tushinova; Boris M. Kuchumov

doi:10.1016/j.jssc.2017.05.031

Nonstoichiometry in the systems Na₂MoO₄–MMoO₄ (M = Co, Cd), crystal structures of Na_3.36Co_1.32(MoO₄)₃, Na_3.13Mn_1.43(MoO₄)₃ and Na_3.72Cd_1.14(MoO₄)₃, crystal chemistry, compositions and ionic conductivity of alluaudite-type double molybdates and tungstates

Sergey F. Solodovnikov, Zoya A. Solodovnikova, Evgeniya S. Zolotova, Vasiliy N. Yudin, Oksana A. Gulyaeva, Yunna L. Tushinova, Boris M. Kuchumov

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

As results of a powder XRD study of sintered samples of the systems Na₂MoO₄–MMoO₄ (M = Co, Cd) quenched in air from 873 K, the literature data on the phase formation and homogeneity ranges of nonstoichiometric double molybdates in these systems were corrected. The compounds are monoclinic alluaudite-type Na_4-2xCo_1+x(MoO₄)₃ (0.05 ≤ x ≤ 0.30) and Na_4-2xCd_1+x(MoO₄)₃ (0.10 ≤ x ≤ 0.40), orthorhombic lyonsite-type Na_2-2yCo_2+y(MoO₄)₃ (0.05 ≤ y ≤ 0.25), and triclinic Na_2-2zCo_2+z(MoO₄)₃ (0.10 ≤ z ≤ 0.40) of the Na₂Mg₅(MoO₄)₆ type. The temperature of the orthorhombic-to-triclinic phase transition was found to be 943 ± 10 K. Crystal structures of the alluaudite-type double molybdates (space group C2/c, Z = 4) with cobalt, manganese, and cadmium were determined. According to the atomic position occupations, the compositions for the crystals were found as Na_3.36Co_1.32(MoO₄)₃ (a = 12.6381(3), b = 13.4888(4), c = 7.1244(2) Å, β = 112.127(1)° R = 0.0207), Na_3.13Mn_1.43(MoO₄)₃ (a = 12.7387(3), b = 13.6716(4), c = 7.1904(2) Å, β = 112.404(1)°, R = 0.0166), and Na_3.72Cd_1.14(MoO₄)₃ (a = 12.804(3), b = 13.913(3), c = 7.326(2) Å, β = 112.63(1)° R = 0.0158). The crystal chemistry and compositions of the alluaudite-type molybdates and tungstates were considered and mainly one-dimensional character of the sodium-ion transport was shown for them. The measured values of the ionic conductivity of sintered samples of Na_3.6M_1.2(MoO₄)₃ (M = Mg, Ni, Zn, Cd) and Na_3.6Mg_1.2(WO₄)₃ exceeds 10⁻³ S cm⁻¹ at 673 K.

Original language	English
Pages (from-to)	121-128
Number of pages	8
Journal	Journal of Solid State Chemistry
Volume	253
DOIs	https://doi.org/10.1016/j.jssc.2017.05.031
Publication status	Published - 1 Sep 2017

Keywords

Alluaudite
Cadmium
Cobalt
Crystal chemistry
Crystal structure
Double molybdates
Double tungstates
Homogeneity range
Ionic conductivity
Manganese
Nonstoichiometry
Sodium
FUMAROLIC SUBLIMATE
STRUCTURE CRISTALLINE
CATHODE MATERIAL
PHOSPHATE
PHASE
PARAGENESIS
NA
DESCRIPTIVE MINERALOGY
IZALCO VOLCANO
EL-SALVADOR

Access to Document

10.1016/j.jssc.2017.05.031

Link to publication in Scopus

Fingerprint Dive into the research topics of 'Nonstoichiometry in the systems Na2MoO4–MMoO4 (M = Co, Cd), crystal structures of Na3.36Co1.32(MoO4)3, Na3.13Mn1.43(MoO4)3 and Na3.72Cd1.14(MoO4)3, crystal chemistry, compositions and ionic conductivity of alluaudite-type double molybdates and tungstates'. Together they form a unique fingerprint.

Cite this

Solodovnikov, S. F., Solodovnikova, Z. A., Zolotova, E. S., Yudin, V. N., Gulyaeva, O. A., Tushinova, Y. L., & Kuchumov, B. M. (2017). Nonstoichiometry in the systems Na₂MoO₄–MMoO₄ (M = Co, Cd), crystal structures of Na_3.36Co_1.32(MoO₄)₃, Na_3.13Mn_1.43(MoO₄)₃ and Na_3.72Cd_1.14(MoO₄)₃, crystal chemistry, compositions and ionic conductivity of alluaudite-type double molybdates and tungstates. Journal of Solid State Chemistry, 253, 121-128. https://doi.org/10.1016/j.jssc.2017.05.031

Solodovnikov, Sergey F. ; Solodovnikova, Zoya A. ; Zolotova, Evgeniya S. ; Yudin, Vasiliy N. ; Gulyaeva, Oksana A. ; Tushinova, Yunna L. ; Kuchumov, Boris M. / Nonstoichiometry in the systems Na₂MoO₄–MMoO₄ (M = Co, Cd), crystal structures of Na_3.36Co_1.32(MoO₄)₃, Na_3.13Mn_1.43(MoO₄)₃ and Na_3.72Cd_1.14(MoO₄)₃, crystal chemistry, compositions and ionic conductivity of alluaudite-type double molybdates and tungstates. In: Journal of Solid State Chemistry. 2017 ; Vol. 253. pp. 121-128.

@article{2abc4109ce974a19b99e7be5057738c7,

title = "Nonstoichiometry in the systems Na2MoO4–MMoO4 (M = Co, Cd), crystal structures of Na3.36Co1.32(MoO4)3, Na3.13Mn1.43(MoO4)3 and Na3.72Cd1.14(MoO4)3, crystal chemistry, compositions and ionic conductivity of alluaudite-type double molybdates and tungstates",

abstract = "As results of a powder XRD study of sintered samples of the systems Na2MoO4–MMoO4 (M = Co, Cd) quenched in air from 873 K, the literature data on the phase formation and homogeneity ranges of nonstoichiometric double molybdates in these systems were corrected. The compounds are monoclinic alluaudite-type Na4-2xCo1+x(MoO4)3 (0.05 ≤ x ≤ 0.30) and Na4-2xCd1+x(MoO4)3 (0.10 ≤ x ≤ 0.40), orthorhombic lyonsite-type Na2-2yCo2+y(MoO4)3 (0.05 ≤ y ≤ 0.25), and triclinic Na2-2zCo2+z(MoO4)3 (0.10 ≤ z ≤ 0.40) of the Na2Mg5(MoO4)6 type. The temperature of the orthorhombic-to-triclinic phase transition was found to be 943 ± 10 K. Crystal structures of the alluaudite-type double molybdates (space group C2/c, Z = 4) with cobalt, manganese, and cadmium were determined. According to the atomic position occupations, the compositions for the crystals were found as Na3.36Co1.32(MoO4)3 (a = 12.6381(3), b = 13.4888(4), c = 7.1244(2) {\AA}, β = 112.127(1)° R = 0.0207), Na3.13Mn1.43(MoO4)3 (a = 12.7387(3), b = 13.6716(4), c = 7.1904(2) {\AA}, β = 112.404(1)°, R = 0.0166), and Na3.72Cd1.14(MoO4)3 (a = 12.804(3), b = 13.913(3), c = 7.326(2) {\AA}, β = 112.63(1)° R = 0.0158). The crystal chemistry and compositions of the alluaudite-type molybdates and tungstates were considered and mainly one-dimensional character of the sodium-ion transport was shown for them. The measured values of the ionic conductivity of sintered samples of Na3.6M1.2(MoO4)3 (M = Mg, Ni, Zn, Cd) and Na3.6Mg1.2(WO4)3 exceeds 10−3 S cm−1 at 673 K.",

keywords = "Alluaudite, Cadmium, Cobalt, Crystal chemistry, Crystal structure, Double molybdates, Double tungstates, Homogeneity range, Ionic conductivity, Manganese, Nonstoichiometry, Sodium, FUMAROLIC SUBLIMATE, STRUCTURE CRISTALLINE, CATHODE MATERIAL, PHOSPHATE, PHASE, PARAGENESIS, NA, DESCRIPTIVE MINERALOGY, IZALCO VOLCANO, EL-SALVADOR",

author = "Solodovnikov, {Sergey F.} and Solodovnikova, {Zoya A.} and Zolotova, {Evgeniya S.} and Yudin, {Vasiliy N.} and Gulyaeva, {Oksana A.} and Tushinova, {Yunna L.} and Kuchumov, {Boris M.}",

year = "2017",

month = sep,

day = "1",

doi = "10.1016/j.jssc.2017.05.031",

language = "English",

volume = "253",

pages = "121--128",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

}

Solodovnikov, SF, Solodovnikova, ZA, Zolotova, ES, Yudin, VN, Gulyaeva, OA, Tushinova, YL & Kuchumov, BM 2017, 'Nonstoichiometry in the systems Na₂MoO₄–MMoO₄ (M = Co, Cd), crystal structures of Na_3.36Co_1.32(MoO₄)₃, Na_3.13Mn_1.43(MoO₄)₃ and Na_3.72Cd_1.14(MoO₄)₃, crystal chemistry, compositions and ionic conductivity of alluaudite-type double molybdates and tungstates', Journal of Solid State Chemistry, vol. 253, pp. 121-128. https://doi.org/10.1016/j.jssc.2017.05.031

Nonstoichiometry in the systems Na₂MoO₄–MMoO₄ (M = Co, Cd), crystal structures of Na_3.36Co_1.32(MoO₄)₃, Na_3.13Mn_1.43(MoO₄)₃ and Na_3.72Cd_1.14(MoO₄)₃, crystal chemistry, compositions and ionic conductivity of alluaudite-type double molybdates and tungstates. / Solodovnikov, Sergey F.; Solodovnikova, Zoya A.; Zolotova, Evgeniya S.; Yudin, Vasiliy N.; Gulyaeva, Oksana A.; Tushinova, Yunna L.; Kuchumov, Boris M.

In: Journal of Solid State Chemistry, Vol. 253, 01.09.2017, p. 121-128.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Nonstoichiometry in the systems Na2MoO4–MMoO4 (M = Co, Cd), crystal structures of Na3.36Co1.32(MoO4)3, Na3.13Mn1.43(MoO4)3 and Na3.72Cd1.14(MoO4)3, crystal chemistry, compositions and ionic conductivity of alluaudite-type double molybdates and tungstates

AU - Solodovnikov, Sergey F.

AU - Solodovnikova, Zoya A.

AU - Zolotova, Evgeniya S.

AU - Yudin, Vasiliy N.

AU - Gulyaeva, Oksana A.

AU - Tushinova, Yunna L.

AU - Kuchumov, Boris M.

PY - 2017/9/1

Y1 - 2017/9/1

N2 - As results of a powder XRD study of sintered samples of the systems Na2MoO4–MMoO4 (M = Co, Cd) quenched in air from 873 K, the literature data on the phase formation and homogeneity ranges of nonstoichiometric double molybdates in these systems were corrected. The compounds are monoclinic alluaudite-type Na4-2xCo1+x(MoO4)3 (0.05 ≤ x ≤ 0.30) and Na4-2xCd1+x(MoO4)3 (0.10 ≤ x ≤ 0.40), orthorhombic lyonsite-type Na2-2yCo2+y(MoO4)3 (0.05 ≤ y ≤ 0.25), and triclinic Na2-2zCo2+z(MoO4)3 (0.10 ≤ z ≤ 0.40) of the Na2Mg5(MoO4)6 type. The temperature of the orthorhombic-to-triclinic phase transition was found to be 943 ± 10 K. Crystal structures of the alluaudite-type double molybdates (space group C2/c, Z = 4) with cobalt, manganese, and cadmium were determined. According to the atomic position occupations, the compositions for the crystals were found as Na3.36Co1.32(MoO4)3 (a = 12.6381(3), b = 13.4888(4), c = 7.1244(2) Å, β = 112.127(1)° R = 0.0207), Na3.13Mn1.43(MoO4)3 (a = 12.7387(3), b = 13.6716(4), c = 7.1904(2) Å, β = 112.404(1)°, R = 0.0166), and Na3.72Cd1.14(MoO4)3 (a = 12.804(3), b = 13.913(3), c = 7.326(2) Å, β = 112.63(1)° R = 0.0158). The crystal chemistry and compositions of the alluaudite-type molybdates and tungstates were considered and mainly one-dimensional character of the sodium-ion transport was shown for them. The measured values of the ionic conductivity of sintered samples of Na3.6M1.2(MoO4)3 (M = Mg, Ni, Zn, Cd) and Na3.6Mg1.2(WO4)3 exceeds 10−3 S cm−1 at 673 K.

AB - As results of a powder XRD study of sintered samples of the systems Na2MoO4–MMoO4 (M = Co, Cd) quenched in air from 873 K, the literature data on the phase formation and homogeneity ranges of nonstoichiometric double molybdates in these systems were corrected. The compounds are monoclinic alluaudite-type Na4-2xCo1+x(MoO4)3 (0.05 ≤ x ≤ 0.30) and Na4-2xCd1+x(MoO4)3 (0.10 ≤ x ≤ 0.40), orthorhombic lyonsite-type Na2-2yCo2+y(MoO4)3 (0.05 ≤ y ≤ 0.25), and triclinic Na2-2zCo2+z(MoO4)3 (0.10 ≤ z ≤ 0.40) of the Na2Mg5(MoO4)6 type. The temperature of the orthorhombic-to-triclinic phase transition was found to be 943 ± 10 K. Crystal structures of the alluaudite-type double molybdates (space group C2/c, Z = 4) with cobalt, manganese, and cadmium were determined. According to the atomic position occupations, the compositions for the crystals were found as Na3.36Co1.32(MoO4)3 (a = 12.6381(3), b = 13.4888(4), c = 7.1244(2) Å, β = 112.127(1)° R = 0.0207), Na3.13Mn1.43(MoO4)3 (a = 12.7387(3), b = 13.6716(4), c = 7.1904(2) Å, β = 112.404(1)°, R = 0.0166), and Na3.72Cd1.14(MoO4)3 (a = 12.804(3), b = 13.913(3), c = 7.326(2) Å, β = 112.63(1)° R = 0.0158). The crystal chemistry and compositions of the alluaudite-type molybdates and tungstates were considered and mainly one-dimensional character of the sodium-ion transport was shown for them. The measured values of the ionic conductivity of sintered samples of Na3.6M1.2(MoO4)3 (M = Mg, Ni, Zn, Cd) and Na3.6Mg1.2(WO4)3 exceeds 10−3 S cm−1 at 673 K.

KW - Alluaudite

KW - Cadmium

KW - Cobalt

KW - Crystal chemistry

KW - Crystal structure

KW - Double molybdates

KW - Double tungstates

KW - Homogeneity range

KW - Ionic conductivity

KW - Manganese

KW - Nonstoichiometry

KW - Sodium

KW - FUMAROLIC SUBLIMATE

KW - STRUCTURE CRISTALLINE

KW - CATHODE MATERIAL

KW - PHOSPHATE

KW - PHASE

KW - PARAGENESIS

KW - NA

KW - DESCRIPTIVE MINERALOGY

KW - IZALCO VOLCANO

KW - EL-SALVADOR

UR - http://www.scopus.com/inward/record.url?scp=85020028213&partnerID=8YFLogxK

U2 - 10.1016/j.jssc.2017.05.031

DO - 10.1016/j.jssc.2017.05.031

M3 - Article

AN - SCOPUS:85020028213

VL - 253

SP - 121

EP - 128

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

SN - 0022-4596

ER -

Solodovnikov SF, Solodovnikova ZA, Zolotova ES, Yudin VN, Gulyaeva OA, Tushinova YL et al. Nonstoichiometry in the systems Na₂MoO₄–MMoO₄ (M = Co, Cd), crystal structures of Na_3.36Co_1.32(MoO₄)₃, Na_3.13Mn_1.43(MoO₄)₃ and Na_3.72Cd_1.14(MoO₄)₃, crystal chemistry, compositions and ionic conductivity of alluaudite-type double molybdates and tungstates. Journal of Solid State Chemistry. 2017 Sep 1;253:121-128. https://doi.org/10.1016/j.jssc.2017.05.031