Non-isothermal kinetics of spin crossover

Mark B. Bushuev, Elena B. Nikolaenkova, Viktor P. Krivopalov

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

Non-isothermal magnetic studies can be used to estimate the activation energy of cooperative spin transition. Model-free isoconversional integral methods give reliable estimates of the activation barrier height for highly cooperative spin crossover systems with wide thermal hysteresis.

Original languageEnglish
Pages (from-to)16955-16959
Number of pages5
JournalPhysical Chemistry Chemical Physics
Volume19
Issue number26
DOIs
Publication statusPublished - 14 Jul 2017

Keywords

  • LARGE THERMAL HYSTERESIS
  • IRON(II) COMPLEXES
  • ACTIVATION-ENERGY
  • TRANSITION
  • STATE
  • INTERPLAY
  • TEMPERATURE
  • LIGANDS

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