Non-isothermal kinetics of spin crossover

Mark B. Bushuev; Elena B. Nikolaenkova; Viktor P. Krivopalov

doi:10.1039/c7cp03442c

Non-isothermal kinetics of spin crossover

Mark B. Bushuev, Elena B. Nikolaenkova, Viktor P. Krivopalov

Analytical Chemistry Section

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Non-isothermal magnetic studies can be used to estimate the activation energy of cooperative spin transition. Model-free isoconversional integral methods give reliable estimates of the activation barrier height for highly cooperative spin crossover systems with wide thermal hysteresis.

Original language	English
Pages (from-to)	16955-16959
Number of pages	5
Journal	Physical Chemistry Chemical Physics
Volume	19
Issue number	26
DOIs	https://doi.org/10.1039/c7cp03442c
Publication status	Published - 14 Jul 2017

Keywords

LARGE THERMAL HYSTERESIS
IRON(II) COMPLEXES
ACTIVATION-ENERGY
TRANSITION
STATE
INTERPLAY
TEMPERATURE
LIGANDS

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title = "Non-isothermal kinetics of spin crossover",

abstract = "Non-isothermal magnetic studies can be used to estimate the activation energy of cooperative spin transition. Model-free isoconversional integral methods give reliable estimates of the activation barrier height for highly cooperative spin crossover systems with wide thermal hysteresis.",

keywords = "LARGE THERMAL HYSTERESIS, IRON(II) COMPLEXES, ACTIVATION-ENERGY, TRANSITION, STATE, INTERPLAY, TEMPERATURE, LIGANDS",

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AU - Bushuev, Mark B.

AU - Nikolaenkova, Elena B.

AU - Krivopalov, Viktor P.

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AB - Non-isothermal magnetic studies can be used to estimate the activation energy of cooperative spin transition. Model-free isoconversional integral methods give reliable estimates of the activation barrier height for highly cooperative spin crossover systems with wide thermal hysteresis.

KW - LARGE THERMAL HYSTERESIS

KW - IRON(II) COMPLEXES

KW - ACTIVATION-ENERGY

KW - TRANSITION

KW - STATE

KW - INTERPLAY

KW - TEMPERATURE

KW - LIGANDS

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JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

SN - 1463-9076

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ER -

Non-isothermal kinetics of spin crossover

Abstract

Keywords

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