Nitrous oxide as a selective oxidant for ketonization of C=C double bonds in organic compounds

Konstantin A. Dubkov, Gennadii I. Panov, Valentin N. Parmon

Research output: Contribution to journalReview articlepeer-review

9 Citations (Scopus)

Abstract

The oxidation chemistry of nitrous oxide (N2O) includes a wide range of both catalytic and non-catalytic selective oxidation reactions. This review summarizes the results of modern experimental and theoretical studies devoted to non-catalytic oxidation reactions ofN2Owith carbon ± carbon double bonds of alkenes and polymers. It is shown that these reactions open up a promising way for the synthesis of diverse carbonyl compounds (ketones and aldehydes) as well as a new type of functionalized oligomersDunsaturated polyketones. Possible applications of unsaturated polyketones, as well as economic aspects of N2O production and use as a selective oxidant are discussed.

Original languageEnglish
Pages (from-to)510-529
Number of pages20
JournalRussian Chemical Reviews
Volume86
Issue number6
DOIs
Publication statusPublished - 1 Jan 2017

Keywords

  • LIQUID-PHASE OXIDATION
  • 1,3-DIPOLAR CYCLOADDITIONS
  • AMMONIA OXIDATION
  • MN/BI/AL CATALYST
  • CARBON-MONOXIDE
  • ALKENES
  • CHEMISTRY
  • RUBBER
  • COPOLYMERIZATION
  • CARBOXIDATION

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