Abstract

The photocatalytic properties of Cd0.3Zn0.7S modified by nickel sulfide and nickel hydroxide were studied. The obtained samples were characterized by a wide range of experimental techniques including X-ray diffraction (XRD), UV-vis diffuse reflectance spectroscopy (DRS), and high resolution transmission electron microscopy (HRTEM). The photocatalytic activity was measured in the hydrogen evolution from aqueous solutions of Na2S/Na2SO3 under visible light irradiation (λ = 450 nm). The highest photocatalytic activity and apparent quantum efficiency (AQE) were 6.12 mmol h-1 g-1 and 22.1%, respectively. A mechanism of the photoinduced transformations of the photocatalysts containing Ni(OH)2, NiS, and Ni3S2 during hydrogen production was proposed.

Original languageEnglish
Pages (from-to)11331-11335
Number of pages5
JournalMaterials Today: Proceedings
Volume4
Issue number11
DOIs
Publication statusPublished - 1 Jan 2017
EventRussia-Japan Conference on Advanced Materials - Synthesis, Processing and Properties of Nanostructures (RJCAM) - Novosibirsk
Duration: 31 Oct 20163 Nov 2016

Keywords

  • Photocatalytic hydrogen production
  • visible light
  • Cd0.3Zn0.7S
  • nickel-based co-catalyst
  • VISIBLE-LIGHT IRRADIATION
  • WATER
  • EVOLUTION
  • NI3S2

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