New Chalcogenide Cobalt Complexes with Diimine Ligands: Synthesis and Crystal Structure

A. Yu Konokhova; M. Yu Afonin; T. S. Sukhikh; S. N. Konchenko

doi:10.1134/S0022476619090105

New Chalcogenide Cobalt Complexes with Diimine Ligands: Synthesis and Crystal Structure

A. Yu Konokhova, M. Yu Afonin, T. S. Sukhikh, S. N. Konchenko

Research output: Contribution to journal › Article › peer-review

Abstract

Reactions of a low-valent cobalt complex [Co(nacnac)(η⁶-C₇H₈)] (1) ((nacnac)⁻ = (HC(C(Me)NC₆H₃-iPr₂)₂)⁻) with selenium and tellurium are studied. Two new binuclear complexes [(Co(nacnac))₂(μ,η²-Se₂)] (2) and [(Co(nacnac))₂(μ,η²-Te₂)] (3) have been isolated and characterized. The structures of the complexes are determined by single crystal X-ray diffraction.

Original language	English
Pages (from-to)	1463-1467
Number of pages	5
Journal	Journal of Structural Chemistry
Volume	60
Issue number	9
DOIs	https://doi.org/10.1134/S0022476619090105
Publication status	Published - 1 Sep 2019

Keywords

binuclear complexes
cobalt
crystal structure
selenium
tellurium
PRECURSOR

Access to Document

10.1134/S0022476619090105

Cite this

@article{7bf224ce09ff40ec91034fa0e5133147,

title = "New Chalcogenide Cobalt Complexes with Diimine Ligands: Synthesis and Crystal Structure",

abstract = "Reactions of a low-valent cobalt complex [Co(nacnac)(η6-C7H8)] (1) ((nacnac)− = (HC(C(Me)NC6H3-iPr2)2)−) with selenium and tellurium are studied. Two new binuclear complexes [(Co(nacnac))2(μ,η2-Se2)] (2) and [(Co(nacnac))2(μ,η2-Te2)] (3) have been isolated and characterized. The structures of the complexes are determined by single crystal X-ray diffraction.",

keywords = "binuclear complexes, cobalt, crystal structure, selenium, tellurium, PRECURSOR",

author = "Konokhova, {A. Yu} and Afonin, {M. Yu} and Sukhikh, {T. S.} and Konchenko, {S. N.}",

year = "2019",

month = sep,

day = "1",

doi = "10.1134/S0022476619090105",

language = "English",

volume = "60",

pages = "1463--1467",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "9",

}

TY - JOUR

T1 - New Chalcogenide Cobalt Complexes with Diimine Ligands

T2 - Synthesis and Crystal Structure

AU - Konokhova, A. Yu

AU - Afonin, M. Yu

AU - Sukhikh, T. S.

AU - Konchenko, S. N.

PY - 2019/9/1

Y1 - 2019/9/1

N2 - Reactions of a low-valent cobalt complex [Co(nacnac)(η6-C7H8)] (1) ((nacnac)− = (HC(C(Me)NC6H3-iPr2)2)−) with selenium and tellurium are studied. Two new binuclear complexes [(Co(nacnac))2(μ,η2-Se2)] (2) and [(Co(nacnac))2(μ,η2-Te2)] (3) have been isolated and characterized. The structures of the complexes are determined by single crystal X-ray diffraction.

AB - Reactions of a low-valent cobalt complex [Co(nacnac)(η6-C7H8)] (1) ((nacnac)− = (HC(C(Me)NC6H3-iPr2)2)−) with selenium and tellurium are studied. Two new binuclear complexes [(Co(nacnac))2(μ,η2-Se2)] (2) and [(Co(nacnac))2(μ,η2-Te2)] (3) have been isolated and characterized. The structures of the complexes are determined by single crystal X-ray diffraction.

KW - binuclear complexes

KW - cobalt

KW - crystal structure

KW - selenium

KW - tellurium

KW - PRECURSOR

UR - http://www.scopus.com/inward/record.url?scp=85073187196&partnerID=8YFLogxK

U2 - 10.1134/S0022476619090105

DO - 10.1134/S0022476619090105

M3 - Article

AN - SCOPUS:85073187196

VL - 60

SP - 1463

EP - 1467

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 9

ER -

New Chalcogenide Cobalt Complexes with Diimine Ligands: Synthesis and Crystal Structure

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this