New Chalcogenide Cobalt Complexes with Diimine Ligands: Synthesis and Crystal Structure

A. Yu Konokhova, M. Yu Afonin, T. S. Sukhikh, S. N. Konchenko

Research output: Contribution to journalArticlepeer-review

Abstract

Reactions of a low-valent cobalt complex [Co(nacnac)(η6-C7H8)] (1) ((nacnac) = (HC(C(Me)NC6H3-iPr2)2)) with selenium and tellurium are studied. Two new binuclear complexes [(Co(nacnac))2(μ,η2-Se2)] (2) and [(Co(nacnac))2(μ,η2-Te2)] (3) have been isolated and characterized. The structures of the complexes are determined by single crystal X-ray diffraction.

Original languageEnglish
Pages (from-to)1463-1467
Number of pages5
JournalJournal of Structural Chemistry
Volume60
Issue number9
DOIs
Publication statusPublished - 1 Sep 2019

Keywords

  • binuclear complexes
  • cobalt
  • crystal structure
  • selenium
  • tellurium
  • PRECURSOR

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