Neutral two-dimensional organometallic-organic hybrid polymers based on pentaphosphaferrocene, bipyridyl linkers and CuCl

M. Elsayed Moussa; B. Attenberger; E. V. Peresypkina; M. Scheer

doi:10.1039/c7dt04286h

Neutral two-dimensional organometallic-organic hybrid polymers based on pentaphosphaferrocene, bipyridyl linkers and CuCl

M. Elsayed Moussa, B. Attenberger, E. V. Peresypkina, M. Scheer

Laboratory for Research Methods in Composition and Structure of Functional Materials

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

The reaction of the P_n ligand complex [Cp∗Fe(η⁵-P₅)] (1: Cp∗ = η⁵-C₅Me₅) with CuCl in the presence of 4,4′-bipyridine or 1,2-di(4-pyridyl)ethylene leads to the formation of three unprecedented neutral 2D organometallic-organic hybrid networks, the constitutional isomers [Cu₂Cl₂{Cp∗Fe(μ₃,η^5:1:1-P₅)}(μ,η^1:1-C₁₀H₈N₂)]_n (2 and 3) and the coordination polymer [(CuCl)₂{Cp∗Fe(μ₃,η^5:1:1-P₅)}(μ,η^1:1-C₁₂H₁₀N₂)]_n (4) with isomeric square (2 and 3) and honeycomb (4) layer topologies.

Original language	English
Pages (from-to)	1014-1017
Number of pages	4
Journal	Dalton Transactions
Volume	47
Issue number	4
DOIs	https://doi.org/10.1039/c7dt04286h
Publication status	Published - 1 Jan 2018

Keywords

COORDINATION NETWORKS
BUILDING-BLOCKS
LIGAND COMPLEX
FRAMEWORKS
BEHAVIOR
DESIGN
2D

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title = "Neutral two-dimensional organometallic-organic hybrid polymers based on pentaphosphaferrocene, bipyridyl linkers and CuCl",

abstract = "The reaction of the Pn ligand complex [Cp∗Fe(η5-P5)] (1: Cp∗ = η5-C5Me5) with CuCl in the presence of 4,4′-bipyridine or 1,2-di(4-pyridyl)ethylene leads to the formation of three unprecedented neutral 2D organometallic-organic hybrid networks, the constitutional isomers [Cu2Cl2{Cp∗Fe(μ3,η5:1:1-P5)}(μ,η1:1-C10H8N2)]n (2 and 3) and the coordination polymer [(CuCl)2{Cp∗Fe(μ3,η5:1:1-P5)}(μ,η1:1-C12H10N2)]n (4) with isomeric square (2 and 3) and honeycomb (4) layer topologies.",

keywords = "COORDINATION NETWORKS, BUILDING-BLOCKS, LIGAND COMPLEX, FRAMEWORKS, BEHAVIOR, DESIGN, 2D",

author = "{Elsayed Moussa}, M. and B. Attenberger and Peresypkina, {E. V.} and M. Scheer",

year = "2018",

month = jan,

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doi = "10.1039/c7dt04286h",

language = "English",

volume = "47",

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journal = "Dalton Transactions",

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T1 - Neutral two-dimensional organometallic-organic hybrid polymers based on pentaphosphaferrocene, bipyridyl linkers and CuCl

AU - Elsayed Moussa, M.

AU - Attenberger, B.

AU - Peresypkina, E. V.

AU - Scheer, M.

PY - 2018/1/1

Y1 - 2018/1/1

N2 - The reaction of the Pn ligand complex [Cp∗Fe(η5-P5)] (1: Cp∗ = η5-C5Me5) with CuCl in the presence of 4,4′-bipyridine or 1,2-di(4-pyridyl)ethylene leads to the formation of three unprecedented neutral 2D organometallic-organic hybrid networks, the constitutional isomers [Cu2Cl2{Cp∗Fe(μ3,η5:1:1-P5)}(μ,η1:1-C10H8N2)]n (2 and 3) and the coordination polymer [(CuCl)2{Cp∗Fe(μ3,η5:1:1-P5)}(μ,η1:1-C12H10N2)]n (4) with isomeric square (2 and 3) and honeycomb (4) layer topologies.

AB - The reaction of the Pn ligand complex [Cp∗Fe(η5-P5)] (1: Cp∗ = η5-C5Me5) with CuCl in the presence of 4,4′-bipyridine or 1,2-di(4-pyridyl)ethylene leads to the formation of three unprecedented neutral 2D organometallic-organic hybrid networks, the constitutional isomers [Cu2Cl2{Cp∗Fe(μ3,η5:1:1-P5)}(μ,η1:1-C10H8N2)]n (2 and 3) and the coordination polymer [(CuCl)2{Cp∗Fe(μ3,η5:1:1-P5)}(μ,η1:1-C12H10N2)]n (4) with isomeric square (2 and 3) and honeycomb (4) layer topologies.

KW - COORDINATION NETWORKS

KW - BUILDING-BLOCKS

KW - LIGAND COMPLEX

KW - FRAMEWORKS

KW - BEHAVIOR

KW - DESIGN

KW - 2D

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U2 - 10.1039/c7dt04286h

DO - 10.1039/c7dt04286h

M3 - Article

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AN - SCOPUS:85041132767

VL - 47

SP - 1014

EP - 1017

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 4

ER -

Neutral two-dimensional organometallic-organic hybrid polymers based on pentaphosphaferrocene, bipyridyl linkers and CuCl

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Keywords

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