Nanocomposite catalysts for transformation of biofuels into syngas and hydrogen: Fundamentals of design and performance, application in structured reactors and catalytic membranes

V. A. Sadykov, M. V. Arapova, E. A. Smal, S. N. Pavlova, L. N. Bobrova, N. F. Eremeev, N. V. Mezentseva, M. N. Simonov

Research output: Chapter in Book/Report/Conference proceedingChapterResearchpeer-review

6 Citations (Scopus)

Abstract

In this review problems related to design and performance of stable and efficient catalysts of biogas/biofuels transformation into syngas and hydrogen based on nanocrystalline oxides with fluorite, perovskite and spinel oxides and their nanocomposites promoted by nanoparticles of Pt group metals and Ni-based alloys are considered. Tailor-made design of these catalysts is based upon elucidation of the relationships between their synthesis procedure, composition, real structure/microstructure, surface properties, oxygen mobility and reactivity determined in a great extent by the metal-support interaction, which requires application of modern sophisticated structural, spectroscopic, kinetic (including in situ FTIRS and isotope transients) methods and mathematical modeling. Thin layers of these optimized catalysts supported on structured heat-conducting substrates, asymmetric supported oxygen or hydrogen separation membranes demonstrated high and stable performance in transformation of biogas and biofuels into syngas and hydrogen.

Original languageEnglish
Title of host publicationCatalysis
EditorsJames J. Spivey, Yi-Fan Han, Dushyant Shekhawat
PublisherRoyal Society of Chemistry
Pages216-241
Number of pages26
ISBN (Electronic)9781788014540
DOIs
Publication statusPublished - 1 Jan 2019

Publication series

NameCatalysis
Volume31
ISSN (Print)0140-0568
ISSN (Electronic)1465-1920

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